Metal oxide surface modification with iron pentacarbonyl: Ligation to surface-tethered 2-(trimethoxysilyl)ethyl-2-pyridine

Langmuir ◽  
1991 ◽  
Vol 7 (3) ◽  
pp. 486-492 ◽  
Author(s):  
M. Mahon ◽  
K. W. Wulser ◽  
M. A. Langell
2013 ◽  
Vol 534 ◽  
pp. 46-52 ◽  
Author(s):  
Kenji Kakiage ◽  
Chie Saito ◽  
Masaki Yamamura ◽  
Toru Kyomen ◽  
Masafumi Unno ◽  
...  

In order to clarify the chemical adsorption property of allylsilane to metal-oxide surface quantitatively and to obtain the information on the reaction conditions for the efficient surface modification, chemical surface modification of nanoporous alumina membranes (NPAMs) by a typical allylsilyl compound of 4-(allyldimethylsilyl) azobenzene was examined. The chemical surface modification was performed by immersing NPAMs into the solutions of the allylsilylazobenzene. The modification was investigated precisely by estimating the amount of the silylazobenzene adsorbed on the NPAM surface using a visible absorption spectroscopy with changing the temperature, solvent, and the concentration of the solution to reveal the effects of the reaction conditions on the adsorption property of the allylsilane to the metal-oxide surface. The solutions with higher temperatures, non-polar solvents, and higher concentrations were shown to be suitable for the efficient surface modification.


2019 ◽  
Vol 571 ◽  
pp. 102-106 ◽  
Author(s):  
Lucas D. Ellis ◽  
Jordi Ballesteros-Soberanas ◽  
Daniel K. Schwartz ◽  
J. Will Medlin

2020 ◽  
Vol 5 (2) ◽  
pp. 294-307 ◽  
Author(s):  
Meysam Keshavarz ◽  
Panagiotis Kassanos ◽  
Bo Tan ◽  
Krishnan Venkatakrishnan

Schematic illustration shows remarkable SERS activities of self-doped Q-structured TiOx with oxygen vacancies compared to the Q-structured TiO2.


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