Structural Stability of Metal Organic Framework MOF-177

2009 ◽  
Vol 1 (1) ◽  
pp. 73-78 ◽  
Author(s):  
Dipendu Saha ◽  
Shuguang Deng
Keyword(s):  
Structural Stability ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A decomposition mechanism for Mn2(DSBDC) metal-organic framework in the presence of water molecules

2021 ◽  
Author(s):  
Thong Nguyen-Minh Le ◽  
Cheng-chau Chiu ◽  
Jer-Lai Kuo
Keyword(s):  
Structural Stability ◽  
Metal Organic Framework ◽  
Decomposition Mechanism ◽  
Water Molecules ◽  
Metal Organic ◽  
Organic Framework

In this work we investigate the effects of water on the structural stability of the Mn2(DSBDC) metal-organic framework (MOF) using DFT-based calculations. It has been found that the adsorption of...

The use of reduced copper metal–organic frameworks to facilitate CuAAC click chemistry

2016 ◽  
Vol 52 (82) ◽  
pp. 12226-12229 ◽  
Author(s):  
Q. Fu ◽  
K. Xie ◽  
S. Tan ◽  
J. M. Ren ◽  
Q. Zhao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Click Chemistry ◽  
Structural Stability ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Copper Metal ◽  
Copper Halide ◽  
Click Reactions ◽  
Metal Organic ◽  
Organic Framework

A reduced copper metal–organic framework (rCu-MOF) containing CuI ions was prepared and employed as a catalyst for ‘Click’ reactions. The rCu-MOF presents higher catalytic activity, good structural stability as well as facile recyclability compared to traditional copper halide catalysts.

scholarly journals Confined crystallization of a HKUST-1 metal–organic framework within mesostructured silica with enhanced structural resistance towards water

2017 ◽  
Vol 5 (42) ◽  
pp. 22305-22315 ◽  
Author(s):  
M. Mazaj ◽  
T. Čendak ◽  
G. Buscarino ◽  
M. Todaro ◽  
N. Zabukovec Logar
Keyword(s):  
Structural Stability ◽  
Metal Organic Framework ◽  
Mesostructured Silica ◽  
Confined Crystallization ◽  
Water Exposure ◽  
Structural Resistance ◽  
Metal Organic ◽  
Organic Framework

A HKUST-1 metal–organic framework was crystallized in the NH2-modified mesostructured silica FDU-12 in order to improve its structural stability upon water exposure.

scholarly journals Significant Enhancement of Structural Stability of the Hyperhalophilic ADH fromHaloferax volcaniivia Entrapment on Metal Organic Framework Support

Langmuir ◽  
2018 ◽  
Vol 34 (28) ◽  
pp. 8274-8280 ◽  
Author(s):  
Cristina Carucci ◽  
Larah Bruen ◽  
Victoria Gascón ◽  
Francesca Paradisi ◽  
Edmond Magner
Keyword(s):  
Structural Stability ◽  
Metal Organic Framework ◽  
Significant Enhancement ◽  
Metal Organic ◽  
Organic Framework

Porous Metal-Organic Framework Materials: Microwave Assisted Synthesis and Oxidative Catalytic Tests

2012 ◽  
Vol 730-732 ◽  
pp. 1024-1029
Author(s):  
André D.S. Barbosa ◽  
Salete S. Balula ◽  
Filipe A. Almeida Paz ◽  
Baltazar de Castro ◽  
Luís Cunha-Silva
Keyword(s):  
Catalytic Activity ◽  
Structural Stability ◽  
Metal Organic Framework ◽  
Microwave Assisted Synthesis ◽  
Ir Absorption ◽  
Oxidation Reactions ◽  
Framework Materials ◽  
Microwave Assisted ◽  
Metal Organic ◽  
Organic Framework

Metal-Organic Framework Materials MIL‑101(Cr) ([Cr3X(H2O)2O(bdc)3]∙n(H2O), where X− = F− or OH−, n ≈ 25 and H2bdc stands for 1,4-benzene-dicarboxylic acid] and MOF‑5(Zn) [Zn4O(bdc)3] were prepared by hydrothermal or solvothermal methods as well as Microwave‑Assisted Synthesis (MWAS), for which the detailed synthetic parameters were optimized. The crystal structures were confirmed by powder X-ray diffraction and the materials were further characterized by FT‑IR absorption spectroscopy. MIL‑101(Cr) and MOF‑5(Zn) showed weak catalytic activity in the oxidation of terpene, thiophene and cis-cyclooctene. Reasonable catalytic activity was observed for MOF-5(Zn) in the epoxidation of cis-cyclooctene and a 100 % of selectivity was observed for the epoxide. The structural stability of the materials was tested under the employed catalytic medium for oxidation reactions. MOF-5(Zn) revealed a remarkable structural stability at high temperature and also in the presence of high oxidant amounts.

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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