scholarly journals Electrochemical Surface Potential Due to Classical Point Charge Models Drives Anion Adsorption to the Air–Water Interface

2012 ◽  
Vol 3 (11) ◽  
pp. 1565-1570 ◽  
Author(s):  
Marcel D. Baer ◽  
Abraham C. Stern ◽  
Yan Levin ◽  
Douglas J. Tobias ◽  
Christopher J. Mundy
Keyword(s):  
Surface Potential ◽  
Point Charge ◽  
Water Interface ◽  
Point Charge Models ◽  
Anion Adsorption ◽  
Air Water Interface ◽  
Classical Point

scholarly journals Surface Potential of the Air/Water Interface

2020 ◽  
Vol 69 (6) ◽  
pp. 519-528 ◽  
Author(s):  
Cuong V. Nguyen ◽  
Hiromichi Nakahara ◽  
Chi M. Phan
Keyword(s):  
Surface Potential ◽  
Water Interface ◽  
Air Water Interface

scholarly journals Surface Potential of MIBC at Air/Water Interface: a Molecular Dynamics Study

2012 ◽  
Vol 10 (0) ◽  
pp. 437-440 ◽  
Author(s):  
C. M. Phan ◽  
H. Nakahara ◽  
O. Shibata ◽  
Y. Moroi ◽  
C. V. Nguyen ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Surface Potential ◽  
Water Interface ◽  
Air Water Interface

The influence of electrolytes on gaseous monolayers II. Ionized films

1955 ◽  
Vol 232 (1189) ◽  
pp. 159-172 ◽  
Keyword(s):  
Surface Potential ◽  
Quaternary Ammonium ◽  
Alkyl Chain ◽  
Electrolyte Concentration ◽  
Ammonium Ion ◽  
Water Interface ◽  
Ammonium Halides ◽  
Air Water Interface ◽  
Good Agreement ◽  
The Ideal

An equation of state for a charged monolayer spread on an aqueous solution of a 1:1 electrolyte at 20°C in the absence of cohesive interactions has been derived, namely II = 2 kT / A-A o + 6.10√ c cosh sinh -1 133/ A √ c 6.10√ c . It has been found to apply to soluble charged films at hydrocarbon/water interfaces. In the case of insoluble monolayers of both alkyl quaternary ammonium halides and sodium alkyl sulphates at the hydrocarbon/water interface there is evidence of considerable ( ~50 %) ion-pair association, and this appears to be even further enhanced at the air/water interface at least for sulphate films. Surface potentials, measured by both the radioactive electrode and vibrating plate condenser techniques have been found to be in good agreement. The surface potential of sulphate monolayers in contrast to the ideal behaviour of quaternary ammonium films has been found to be dependent not only on the electrolyte concentration and film area but also on the nature of the interface, the nature of the substrate and at the air/water interface on the chain length. This has been attributed to a reorientation of the film molecules at the interface. Differences in the surface potential behaviour of sulphate and quaternary ammonium films are explained by suggesting that whereas with the sulphate film restricted rotation about the C—O bond can lead to different configurations of the sulphate ion with respect to the alkyl chain, only one configuration is possible for the symmetrical quaternary ammonium ion. Surface potential evidence indicates that contrary to what has been suggested previously, sulphate monolayers are completely dissociated in the acid-base sense.

Reactions of Retinals in a Model Membrane System

1973 ◽  
Vol 28 (3-4) ◽  
pp. 157-164 ◽  
Author(s):  
Seymour S. Brody
Keyword(s):  
Quantum Yield ◽  
Surface Potential ◽  
Membrane System ◽  
Model Membrane ◽  
Water Interface ◽  
Interface Area ◽  
Air Water Interface ◽  
Monomolecular Films

Monomolecular films of 9-cis, 11-cis, 13-cis and all-trans retinal were formed at an air-water interface. Area/molecule and surface potential were measured before, during and after illumination. The initial quantum yield of the photoisomerization of 9-cis retinal was 0.25. Irradiation of a retinal monolayer resulted in 30 to 60 mVolt changes in surface potential. Complexation of retinals with lysine and cysteine were studied.

Solvent accessibility and hydrophobicity in the adsorption of alkylammonium cations at air/water and Hg/water interfaces. Part 1. Behavior at the air/water interface in relation to hydration properties

1981 ◽  
Vol 59 (13) ◽  
pp. 1978-1986 ◽  
Author(s):  
R. Bennes ◽  
B. E. Conway
Keyword(s):  
Surface Potential ◽  
Hydrophobic Interactions ◽  
Solvent Accessibility ◽  
Water Interface ◽  
Ion Distribution ◽  
Progressive Change ◽  
Hydration Properties ◽  
Air Water Interface ◽  
Electrostatic And Hydrophobic Interactions

By means of adsorption and surface-potential studies on a series of R4−nN+Hn perchlorates at the air/water interface, the role of hydrophobic and hydrophilic interaction in the adsorption and ion distribution of these salts near the air/water interface is examined. While the adsorption of the alkylamine ions increases as n decreases from three to zero, inclusive, the surface-potential change accompanying the adsorption decreases. This effect is interpreted in terms of opposing hydrophilic, electrostatic and hydrophobic interactions between the organic ion and water near the liquid surface, leading to a progressive change of double-layer ion distribution. In Part II, comparative studies of the same series of compounds at the Hg/water interface are reported.

Surface Potential of Methyl Isobutyl Carbinol Adsorption Layer at the Air/Water Interface

2012 ◽  
Vol 116 (3) ◽  
pp. 980-986 ◽  
Author(s):  
Chi M. Phan ◽  
Hiromichi Nakahara ◽  
Osamu Shibata ◽  
Yoshikiyo Moroi ◽  
Thu N. Le ◽  
...  
Keyword(s):  
Surface Potential ◽  
Adsorption Layer ◽  
Water Interface ◽  
Methyl Isobutyl ◽  
Air Water Interface

Interactions Between Ferredoxin and Chlorophyll in a Monolayer System

1971 ◽  
Vol 26 (9) ◽  
pp. 922-929 ◽  
Author(s):  
Seymour Steven Brody
Keyword(s):  
Surface Tension ◽  
Quantum Yield ◽  
Chlorophyll A ◽  
Surface Potential ◽  
Nitrogen Atmosphere ◽  
Water Interface ◽  
Monomolecular Film ◽  
Air Water Interface ◽  
Surface Active

Ferredoxin (Fd) is surface active; both its area/molecule, A, and surface potential, ΔV, (at an air-water interface) vary with the pH of the subphase. From the surface isotherms (at pH 7.7) A and ΔV are 167 A2 and 170 ± 20 mV, respectively, when the surface tension is 10 dyne/cm.Fd and chlorophyll a (Chl) appear to form a mixed monomolecular film. At pH 7.7 a maximum interaction between Fd and Chl is observed when the monolayer contains a mole ratio of Fd/Chl ≅ 2. Irradiaion of Chl-Fd films, in nitrogen atmosphere, results in a bleaching of Chl and an increase of ΔV. The quantum yield for this bleaching is estimated to be 0.4.

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