Charge Separation and Trapping in N-Doped TiO2 Photocatalysts: A Time-Resolved Microwave Conductivity Study

2010 ◽  
Vol 1 (22) ◽  
pp. 3261-3265 ◽  
Author(s):  
Ryuzi Katoh ◽  
Akihiro Furube ◽  
Ken-ichi Yamanaka ◽  
Takeshi Morikawa
1991 ◽  
Author(s):  
John M. Warman ◽  
Stephan A. Jonker ◽  
Matthijs P. de Haas ◽  
Jan W. Verhoeven ◽  
Michael N. Paddon-Row

2015 ◽  
Vol 3 (30) ◽  
pp. 15466-15472 ◽  
Author(s):  
Shohei Nakajima ◽  
Ryuzi Katoh

Charge carrier dynamics in various commercially available TiO2 photocatalysts was studied by means of the time-resolved microwave conductivity (TRMC) technique.


Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 679 ◽  
Author(s):  
Siyoung Na ◽  
Sohyeon Seo ◽  
Hyoyoung Lee

Research into the development of efficient semiconductor photocatalytic materials is a promising approach to solving environmental and energy problems worldwide. Among these materials, TiO2 photocatalysts are one of the most commonly used due to their efficient photoactivity, high stability, low cost and environmental friendliness. However, since the UV content of sunlight is less than 5%, the development of visible light-activated TiO2-based photocatalysts is essential to increase the solar energy efficiency. Here, we review recent works on advanced visible light-activated Ti3+-self-doped TiO2 (Ti3+–TiO2) photocatalysts with improved electronic band structures for efficient charge separation. We analyze the different methods used to produce Ti3+–TiO2 photocatalysts, where Ti3+ with a high oxygen defect density can be used for energy production from visible light. We categorize advanced modifications in electronic states of Ti3+–TiO2 by improving their photocatalytic activity. Ti3+–TiO2 photocatalysts with large charge separation and low recombination of photogenerated electrons and holes can be practically applied for energy conversion and advanced oxidation processes in natural environments and deserve significant attention.


Author(s):  
Khang Cao Nguyen ◽  
Nghia Manh Nguyen ◽  
Van Quoc Duong ◽  
Khanh Van Nguyen ◽  
Hung Manh Nguyen ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 403
Author(s):  
Armelle Sengele ◽  
Didier Robert ◽  
Nicolas Keller ◽  
Valérie Keller

In the context of the increase in chemical threat due to warfare agents, the development of efficient methods for destruction of Chemical Warfare Agents (CWAs) are of first importance both for civilian and military purposes. Amongst possible methods for destruction of CWAs, photocatalytic oxidation is an alternative one. The present paper reports on the preparation of Ta and Sn doped TiO2 photocatalysts immobilized on β-SiC foams for the elimination of diethyl sulfide (DES) used as a model molecule mimicking Yperite (Mustard Gas) in gaseous phase. Photo-oxidation efficiency of doped TiO2 catalyst has been compared with TiO2-P25. Here, we demonstrate that the Sn doped-TiO2 with a Polyethylene glycol (PEG)/TiO2 ratio of 7 exhibits the best initial activity (up to 90%) but is deactivates more quickly than Ta doped-TiO2 (40% after 800 min). The activity of the catalysts is strongly influenced by the adsorption properties of the support, as β-SiC foams adsorb DES and other sulfur compounds. This adsorption makes it possible to limit the poisoning of the catalysts and to maintain an acceptable conversion rate even after ten hours under continuous DES flow. Washing with NaOH completely regenerates the catalyst after a firs treatment and even seems to “wash” it by removing impurities initially present on the foams.


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