Statistical Mechanics and Molecular Simulation of Adsorption in Microporous Materials:  Pillared Clays and Carbon Molecular Sieve Membranes†

2000 ◽  
Vol 104 (16) ◽  
pp. 3892-3905 ◽  
Author(s):  
Jaleh Ghassemzadeh ◽  
Lifang Xu ◽  
Theodore T. Tsotsis ◽  
Muhammad Sahimi
Keyword(s):  
Statistical Mechanics ◽  
Molecular Simulation ◽  
Molecular Sieve ◽  
Microporous Materials ◽  
Pillared Clays ◽  
Carbon Molecular Sieve

scholarly journals A MEMS µ-Preconcentrator Employing a Carbon Molecular Sieve Membrane for Highly Volatile Organic Compound Sampling

Chemosensors ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 104
Author(s):  
Hung-Yang Kuo ◽  
Wei-Riu Cheng ◽  
Tzu-Heng Wu ◽  
Horn-Jiunn Sheen ◽  
Chih-Chia Wang ◽  
...  
Keyword(s):  
Organic Compound ◽  
Organic Compounds ◽  
Volatile Organic Compound ◽  
Molecular Sieve ◽  
Amplification Factor ◽  
Microfluidic Channel ◽  
Carbon Molecular Sieve ◽  
Volatile Organic ◽  
Chromatographic Peaks ◽  
Gaseous Toluene

This paper presents the synthesis and evaluation of a carbon molecular sieve membrane (CMSM) grown inside a MEMS-fabricated μ-preconcentrator for sampling highly volatile organic compounds. An array of µ-pillars measuring 100 µm in diameter and 250 µm in height were fabricated inside a microfluidic channel to increase the attaching surface for the CMSM. The surface area of the CMSM was measured as high as 899 m2/g. A GC peak amplification factor >2 × 104 was demonstrated with gaseous ethyl acetate. Up to 1.4 L of gaseous ethanol at the 100 ppb level could be concentrated without exceeding the capacity of this microchip device. Sharp desorption chromatographic peaks (<3.5 s) were obtained while using this device directly as a GC injector. Less volatile compounds such as gaseous toluene, m-xylene, and mesitylene appeared to be adsorbed strongly on CMSM, showing a memory effect. Sampling parameters such as sample volatilities, sampling capacities, and compound residual issues were empirically determined and discussed.

Carbon molecular sieve based micro-matrix-solid-phase dispersion for the extraction of polyphenols in pomegranate peel by UHPLC-Q-TOF/MS

2018 ◽  
Vol 39 (17) ◽  
pp. 2218-2227 ◽  
Author(s):  
Li-Jing Du ◽  
Jian-Ping Huang ◽  
Bin Wang ◽  
Chen-Hui Wang ◽  
Qiu-Yan Wang ◽  
...  
Keyword(s):  
Molecular Sieve ◽  
Solid Phase ◽  
Carbon Molecular Sieve ◽  
Pomegranate Peel ◽  
Matrix Solid Phase Dispersion ◽  
Phase Dispersion ◽  
Tof Ms

scholarly journals A Self‐Consistent Model for Sorption and Transport in Polyimide‐Derived Carbon Molecular Sieve Gas Separation Membranes

2020 ◽  
Vol 132 (46) ◽  
pp. 20523-20527
Author(s):  
Oishi Sanyal ◽  
Samuel S. Hays ◽  
Nicholas E. León ◽  
Yoseph A. Guta ◽  
Arun K. Itta ◽  
...  
Keyword(s):  
Gas Separation ◽  
Molecular Sieve ◽  
Carbon Molecular Sieve ◽  
Separation Membranes ◽  
Gas Separation Membranes ◽  
Consistent Model ◽  
Self Consistent
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