The Dynamics of Electronic Energy Transfer in Novel Multiporphyrin Functionalized Dendrimers:  A Time-Resolved Fluorescence Anisotropy Study

2000 ◽  
Vol 104 (12) ◽  
pp. 2596-2606 ◽  
Author(s):  
Kenneth P. Ghiggino ◽  
Joost N. H. Reek ◽  
Maxwell J. Crossley ◽  
Anton W. Bosman ◽  
Albert P. H. J. Schenning ◽  
...  
2000 ◽  
Vol 323 (1-2) ◽  
pp. 117-124 ◽  
Author(s):  
Yoshinobu Nishimura ◽  
Akira Yasuda ◽  
Shammai Speiser ◽  
Iwao Yamazaki

2003 ◽  
Vol 102-103 ◽  
pp. 278-282 ◽  
Author(s):  
Shammai Speiser ◽  
Miki Hasegawa ◽  
Shigendo Enomoto ◽  
Toshihiko Hoshi ◽  
Katsuyuki Igarashi ◽  
...  

Author(s):  
V. Fidler ◽  
P. Kapusta ◽  
M. Nepras ◽  
J. Schroeder ◽  
I.V. Rubtsov ◽  
...  

Ultrafast time resolved fluorescence anisotropy decay measurements were performed to gain insight into the energy gap dependence of donor-acceptor inter-chromophoric coupling within one supra-molecule. Three new compounds, each consisting of two semi-rigidly linked and strongly coupled chromophores, were designed and synthesized for this study. Their general structure is donor-spacer-acceptor, where "donor" is phenylamino, pyrenylamino, or benzanthronylamino moiety, and acceptor is aminobenzanthrone. While being similar structurally, the compounds differ significantly in the excitation energy difference of the two chromophores in a supra-molecule. Experimental data show an ultrafast initial fluorescence emission anisotropy decrease (within less then 1 ps) when the excited state energies of the interacting chromophores are close to each other or equal. No such fast fluorescence anisotropy dynamics is observed for a compound with a large energy gap.


1988 ◽  
Vol 122 (3) ◽  
pp. 431-442 ◽  
Author(s):  
N.P. Ernsting ◽  
M. Kaschke ◽  
J. Kleinschmidt ◽  
K.H. Drexhage ◽  
V. Huth

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