Effect of Surfactant Aggregation in the Adsorption Layer at the Liquid/Fluid Interface on the Shape of the Surface Pressure Isotherm

2000 ◽  
Vol 104 (24) ◽  
pp. 5744-5749 ◽  
Author(s):  
V. B. Fainerman ◽  
E. V. Aksenenko ◽  
R. Miller
2003 ◽  
Vol 771 ◽  
Author(s):  
G. Panzera ◽  
S. Conoci ◽  
S. Coffa ◽  
B. Pignataro ◽  
S. Sortino ◽  
...  

AbstractThin films (1-24 layers) of bis-zinc ethane-bridged porphyrin dimer (1) have been transferred on solid surfaces, by the Langmuir- Schäfer (LS) horizontal method. The related surface pressurearea isotherm curve shows that in dependence of the film pressure different condensed phases may occur in the monolayer. The inspection of the monolayer by Brewster Angle Microscopy (BAM) reveals the presence of peculiar networks whose structural features seemingly change upon film compression. On the other hand, the Scanning Force Microscopy (SFM) analysis performed on LS films shows fractal networks constituted by nanoscopic supramolecular aggregates, whose shape and size depend again on the LS deposition surface pressure. Finally, also UV-vis spectroscopy measurements indicates that the absorption is almost linearly related to the film thickness that is directly connected to the surface pressure.


AIAA Journal ◽  
2000 ◽  
Vol 38 ◽  
pp. 266-274
Author(s):  
Michael C. Goody ◽  
Roger L. Simpson ◽  
Christopher J. Chesnakas

AIAA Journal ◽  
2000 ◽  
Vol 38 ◽  
pp. 1765-1767
Author(s):  
A. Gatto ◽  
N. A. Ahmed ◽  
R. D. Archer

Author(s):  
Manjinder Saini ◽  
Jonathon Naughton ◽  
Taro Yamashita ◽  
Hiroki Nagai ◽  
Keisuke Asai

2002 ◽  
Vol 67 (11) ◽  
pp. 1579-1588 ◽  
Author(s):  
Dorota Sieńko ◽  
Dorota Gugała ◽  
Jolanta Nieszporek ◽  
Joanna Jankowska ◽  
Jadwiga Saba

The results of thermodynamic analysis of o-toluidine adsorption on a mercury electrode in the presence of various butan-1-ol amounts complete our previous studies on properties of mixed adsorption layers of toluidine isomers-butan-1-ol. The values of the relative surface excess Γ'°T obtained for o-toluidine show that adsorption of this compound decreases with increasing of butan-1-ol concentration. Analysis of adsorption parameters derived from the Frumkin isotherm indicates that in the presence of 0.33 M BuOH in 1 M NaClO4 with adjusted pH 3 as supporting electrolyte, ∆G0 values for o-toluidine are the highest and, at the same time, the strongest repulsive interaction occurs. In the presence of 0.11 M butan-1-ol, smaller values of ∆G0 for o-toluidine correspond to weaker repulsive interaction. Therefore the change of the Γ'°T value for o-toluidine as a function of butan-1-ol concentration is the result of mutual changes of ∆G0 and interaction constant A between adsorbate molecules.


2021 ◽  
Vol 11 (2) ◽  
pp. 527
Author(s):  
Tim Tofan ◽  
Harald Kruggel-Emden ◽  
Vytautas Turla ◽  
Raimondas Jasevičius

The numerical simulation and analysis of the ejection of an ink droplet through a nozzle as well its motion through air until its contact with a surface and taking up of a stable form is performed. The fluid flow is modeled by the incompressible Navier–Stokes equations with added surface tension. The presented model can be solved using either a level set or a phase field method to track the fluid interface. Here, the level set method is used to determinate the interface between ink and air. The presented work concentrates on the demonstration how to check the suitability of ink for inkjet printhead nozzles, for instance, for the use in printers. The results such as velocity, change of size, and volume dependence on time of an ink droplet are presented. Recommendations for the use of specific inks are also given.


Sign in / Sign up

Export Citation Format

Share Document