New Approach to Evaluate Pore Size Distributions and Surface Areas for Hydrophobic Mesoporous Solids

1999 ◽  
Vol 103 (48) ◽  
pp. 10670-10678 ◽  
Author(s):  
Michal Kruk ◽  
Valentyn Antochshuk ◽  
Mietek Jaroniec ◽  
Abdelhamid Sayari
Keyword(s):  
Pore Size ◽  
Size Distributions ◽  
New Approach ◽  
Surface Areas ◽  
Pore Size Distributions ◽  
Mesoporous Solids

An Algorithm for Modeling the Covalent Triazine-Based Frameworks

2019 ◽  
Vol 956 ◽  
pp. 212-217
Author(s):  
Ce Song ◽  
Zhao Liang Meng ◽  
Jin Yan Wang ◽  
Fang Yuan Hu ◽  
Xi Gao Jian
Keyword(s):  
Theoretical Model ◽  
Pore Size ◽  
Structural Properties ◽  
Experimental Results ◽  
Size Distributions ◽  
Design Strategies ◽  
Surface Areas ◽  
Pore Size Distributions ◽  
Amorphous Structures ◽  
Acceptable Consistency

An algorithm for generating the representative structures of covalent triazine-based frameworks (CTFs) is proposed, and examined by being applied to the framework synthesized by the trimerization of dicyanobenzene. The algorithm is validated by the comparison between the calculated and experimental results of the structural properties such as surface areas and pore size distributions, which shows acceptable consistency. Moreover, the presented modeling approach can be expected for more extensive use for other CTFs. Thus the simulated atomistic strucutures produced from the modeling method can improve the understanding for amorphous structures of the CTFs which have already been developed, as well as predict the theoretical model of new CTFs, and provide useful design strategies for the future experimental efforts.

Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

2020 ◽  
Vol 56 (31) ◽  
pp. 4273-4275 ◽  
Author(s):  
Thien S. Nguyen ◽  
Cafer T. Yavuz
Keyword(s):  
Pore Size ◽  
Co2 Capture ◽  
Size Distributions ◽  
Network Polymers ◽  
Surface Areas ◽  
Nitrogen Effect ◽  
Pore Size Distributions ◽  
The Impact

The impact of nitrogen atoms on CO2 binding was evaluated for two isostructural porous bisimidazole-linked polymers (BILPs), which serendipitously had identical surface areas and pore size distributions, a very rare observation.

In situ formed methyl-co-(bis-R) silsesquioxane based polymer networks with solvent controlled pore size distributions and high surface areas

2020 ◽  
Vol 4 (3) ◽  
pp. 851-861 ◽  
Author(s):  
Nai-hsuan Hu ◽  
Chamika U. Lenora ◽  
Timothy A. May ◽  
Nathan C. Hershberger ◽  
Joseph C. Furgal
Keyword(s):  
Pore Size ◽  
High Surface ◽  
Polymer Networks ◽  
Size Distributions ◽  
Surface Areas ◽  
Pore Size Distributions

Specific pore size distributions of synthesized methylsilsesquioxane-based network materials stem from a combination of the solvation of monomers and growing oligomers, as well as miscibility of water in tested solvents; enabling specific analyte uptake materials.

scholarly journals Estimating Pore-Size Distributions of Moderately Hydrophobic Mesoporous Solids

2013 ◽  
Vol 31 (2-3) ◽  
pp. 153-164 ◽  
Author(s):  
Kamil Gierszal ◽  
Michal Kruk ◽  
Mietek Jaroniec
Keyword(s):  
Pore Size ◽  
Size Distributions ◽  
Pore Size Distributions ◽  
Mesoporous Solids

CHARACTERIZATION OF PORE SIZE DISTRIBUTIONS USING NON-NEWTONIAN FLUIDS

2020 ◽  
Author(s):  
Scott C. Hauswirth ◽  
◽  
Majdi Abou Najm ◽  
Christelle Basset
Keyword(s):  
Pore Size ◽  
Newtonian Fluids ◽  
Size Distributions ◽  
Pore Size Distributions

Preparation of P(GMA-co-EGDMA) Monolithic Columns with Adjustable Porous Properties

2014 ◽  
Vol 936 ◽  
pp. 942-949 ◽  
Author(s):  
Hao Tian Zhang ◽  
Qiu Yu Zhang ◽  
Bao Liang Zhang ◽  
Chun Mei Li
Keyword(s):  
Pore Size ◽  
Monolithic Column ◽  
Organic Polymer ◽  
Monolithic Columns ◽  
Size Distributions ◽  
Notable Effect ◽  
Pore Size Distributions ◽  
Porous Properties ◽  
Glass Tubes ◽  
First Time

Porous properties have notable effect on separating effect of organic polymer-based monolithic column. Different applications of monolithic columns require tailored pore size distributions. On account of that, P(GMA-co-EGDMA) monolithic columns were prepared with novel ternary porogenic agents. Glass tubes was chosen as polymerization mold. Moreover, factors influencing the inner pore morphology, pore size and specific surface area were investigated systematically. The results showed that the increasing of the solubility of porogenic agents and the amount of crosslinker, the decreasing of the amount of porogenic agents and temperature rising all could give rise to the decreasing of pore size. Remarkably, the effect of initiator was studied for the first time. The results showed that amount of initiator had no remarkable influence on porous properties. By controlling effect factors, P(GMA-co-EGDMA) Monolithic Columns with pore size from dozens to thousands of nanometer, which can be applied in separation of molecules with different size.

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