Low-Temperature Matrix Isolation Studies of BCl(N3)2:  Infrared Spectra and Photolysis Processes

1999 ◽  
Vol 103 (48) ◽  
pp. 9661-9668 ◽  
Author(s):  
Michael J. Travers ◽  
Erika L. Eldenburg ◽  
Julanna V. Gilbert
Keyword(s):  
Low Temperature ◽  
Infrared Spectra ◽  
Matrix Isolation ◽  
Temperature Matrix

ChemInform Abstract: Low-Temperature Matrix Isolation Studies of BCl(N3)2: Infrared Spectra and Photolysis Processes.

ChemInform ◽  
2010 ◽  
Vol 31 (8) ◽  
pp. no-no
Author(s):  
Michael J. Travers ◽  
Erika L. Eldenburg ◽  
Julanna V. Gilbert
Keyword(s):  
Low Temperature ◽  
Infrared Spectra ◽  
Matrix Isolation ◽  
Temperature Matrix

Hydrogen sulphide – halogen complexes studied by matrix isolation vibrational spectroscopy

1985 ◽  
Vol 63 (7) ◽  
pp. 1705-1707 ◽  
Author(s):  
U. P. Agarwal ◽  
A. J. Barnes ◽  
W. J. Orville-Thomas
Keyword(s):  
Low Temperature ◽  
Vibrational Spectroscopy ◽  
Infrared Spectra ◽  
Hydrogen Sulphide ◽  
Matrix Isolation ◽  
Reaction Products ◽  
Hydrogen Halides ◽  
Stretching Vibration

Infrared spectra are reported of mixtures of hydrogen sulphide with chlorine or bromine in low-temperature argon or nitrogen matrices. The H2S … Cl2 and H2S … Br2 complexes were identified from the perturbed halogen stretching vibration. Absorptions due to the corresponding hydrogen halides provided evidence that reaction was occurring between the hydrogen sulphide and halogen (despite the use of a twin-jet deposition), and other reaction products were tentatively identified from the observed absorptions.

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