Vibrational Spectrum of the J-625 Intermediate in the Room Temperature Bacteriorhodopsin Photocycle

2000 ◽  
Vol 104 (18) ◽  
pp. 4130-4139 ◽  
Author(s):  
G. H. Atkinson ◽  
L. Ujj ◽  
Yidong Zhou
Keyword(s):  
Vibrational Spectrum ◽  
Room Temperature ◽  
Bacteriorhodopsin Photocycle

Some investigations of the chemistry of tellurium chloride pentafluoride, its reaction with caesium fluoride, and the preparation of cis and trans methoxytellurium(VI) chloride tetrafluoride, (CH3O)TeClF4

1984 ◽  
Vol 62 (8) ◽  
pp. 1477-1482 ◽  
Author(s):  
Lawrence J. Lawlor ◽  
Jack Passmore
Keyword(s):  
Vibrational Spectrum ◽  
Trans Isomer ◽  
Room Temperature ◽  
Temperature Range ◽  
Cis And Trans

The reaction of TeClF5 with CH3OH, and CH3OSiMe3, leads to a mixture of cis- and trans-(CH3O)TeClF4 in a ratio of 1:6, as well as some unidentified Te(IV) product. The vibrational spectrum of the 1:6 mixture of cis- and trans-(CH3O)TeClF4 was accounted for on the basis of the predominant pseudo-C4vtrans isomer. TeClF5 is unreactive towards anhydrous HF, SbF5, AlCl3, SO2, F2, and ClF at room temperature. Over the temperature range 70–250 °C it thermally decomposes to TeF6, TeF4, and Cl2. It slowly reacts with CsF to form CsTeF5, TeF6, Cl2, and small amounts of ClF, and with HNMe2 it is also reduced to form TeF4•HNMe2.

Photochemistry of K-590 in the Room-Temperature Bacteriorhodopsin Photocycle†

2000 ◽  
Vol 104 (46) ◽  
pp. 10827-10834
Author(s):  
J. K. Delaney ◽  
P. K. Schmidt ◽  
T. L. Brack ◽  
G. H. Atkinson
Keyword(s):  
Room Temperature ◽  
Bacteriorhodopsin Photocycle

scholarly journals Vibrational Spectrum of the Lumi Intermediate in the Room Temperature Rhodopsin Photo-Reaction

1998 ◽  
Vol 74 (3) ◽  
pp. 1492-1501 ◽  
Author(s):  
Laszlo Ujj ◽  
Frank Jäger ◽  
George H. Atkinson
Keyword(s):  
Vibrational Spectrum ◽  
Room Temperature
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