Ordering of Silicate Layers by Hydrogen-Bonding Networks:  Solid State NMR Investigation of the Perfect Three-Dimensional Registration in the Layer Silicate RUB-18

1999 ◽  
Vol 103 (29) ◽  
pp. 5933-5938 ◽  
Author(s):  
Ingo Wolf ◽  
Hermann Gies ◽  
Colin A. Fyfe
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Three Dimensional ◽  
Layer Silicate ◽  
Hydrogen Bonding Networks ◽  
Silicate Layers

A Solid-State NMR Study of Hydrogen-Bonding Networks and Ion Dynamics in Benzimidazole Salts

2007 ◽  
Vol 111 (20) ◽  
pp. 5602-5609 ◽  
Author(s):  
Jason W. Traer ◽  
James F. Britten ◽  
Gillian R. Goward
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Ion Dynamics ◽  
Nmr Study ◽  
Hydrogen Bonding Networks

Characterisation of hydrogen bonding networks in RNAs via magic angle spinning solid state NMR spectroscopy

2005 ◽  
Vol 31 (4) ◽  
pp. 331-336 ◽  
Author(s):  
Kerstin Riedel ◽  
Jörg Leppert ◽  
Oliver Ohlenschläger ◽  
Matthias Görlach ◽  
Ramadurai Ramachandran
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Solid State Nmr Spectroscopy ◽  
Hydrogen Bonding Networks ◽  
Angle Spinning

scholarly journals Crystal structure of 2-cyano-1-methylpyridinium tetrafluoroborate

2015 ◽  
Vol 71 (10) ◽  
pp. o697-o698 ◽  
Author(s):  
Francesca A. Vaccaro ◽  
Lynn V. Koplitz ◽  
Joel T. Mague
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Three Dimensional ◽  
Asymmetric Unit ◽  
State Structure ◽  
Solid State Structure ◽  
Two Component

The asymmetric unit of the title salt, C7H7N2+·BF4−, comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H...F hydrogen bonding, that are approximately parallel to (010). Further C—H...F hydrogen bonding consolidates the three-dimensional architecture. The sample was refined as a two-component non-merohedral twin.

scholarly journals Temperature-Dependent Solid-State NMR Proton Chemical-Shift Values and Hydrogen Bonding

2021 ◽  
Author(s):  
Alexander A. Malär ◽  
Laura A. Völker ◽  
Riccardo Cadalbert ◽  
Lauriane Lecoq ◽  
Matthias Ernst ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Chemical Shift ◽  
Hydrogen Bonds ◽  
Solid State Nmr ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Proton Chemical Shift ◽  
Temperature Dependent

Temperature-dependent NMR experiments are often complicated by rather long magnetic-field equilibration times, for example occurring upon a change of sample temperature. We demonstrate that the fast temporal stabilization of the magnetic field can be achieved by actively stabilizing the temperature which allows to quantify the weak temperature dependence of the proton chemical shift which can be diagnostic for the presence of hydrogen bonds. Hydrogen bonding plays a central role in molecular recognition events from both fields, chemistry and biology. Their direct detection by standard structure determination techniques, such as X-ray crystallography or cryo-electron microscopy, remains challenging due to the difficulties of approaching the required resolution, on the order of 1 Å. We herein explore a spectroscopic approach using solid-state NMR to identify protons engaged in hydrogen bonds and explore the measurement of proton chemical-shift temperature coefficients. Using the examples of a phosphorylated amino acid and the protein ubiquitin, we show that fast Magic-Angle Spinning (MAS) experiments at 100 kHz yield sufficient resolution in proton-detected spectra to quantify the rather small chemical-shift changes upon temperature variations.<br>

scholarly journals Hydrogen Bonding of Water Confined in Controlled-Pore Glass 10-75 Studied by1H-Solid State NMR

2007 ◽  
Vol 221 (1) ◽  
pp. 155-168 ◽  
Author(s):  
A. Vyalikh ◽  
Th. Emmler ◽  
B. Grünberg ◽  
Y. Xu ◽  
I. Shenderovich ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Controlled Pore Glass ◽  
Pore Glass

scholarly journals Investigation of glycerol hydrogen-bonding networks in choline chloride/glycerol eutectic-forming liquids using neutron diffraction

2019 ◽  
Vol 21 (39) ◽  
pp. 21782-21789 ◽  
Author(s):  
Adam H. Turner ◽  
John D. Holbrey
Keyword(s):  
Hydrogen Bonding ◽  
Neutron Diffraction ◽  
Neutron Scattering ◽  
Choline Chloride ◽  
Three Dimensional ◽  
Hydrogen Bonding Networks ◽  
Hydrogen Bonding Network

Neutron scattering reveals the persistent three-dimensional hydrogen-bonding network between glycerol molecules in the 1 : 2 choline chloride/glycerol eutectic.

scholarly journals Hydrogen-Bonding Interactions in T-2 Toxin Studied Using Solution and Solid-State NMR

Toxins ◽  
2011 ◽  
Vol 3 (10) ◽  
pp. 1310-1331 ◽  
Author(s):  
Praveen Chaudhary ◽  
Roxanne A. Shank ◽  
Tony Montina ◽  
James T. Goettel ◽  
Nora A. Foroud ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Hydrogen Bonding Interactions
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