Solvent Effects on the Complex Formation of Benzophenone Ketyl Radical and Triethylamine

1999 ◽  
Vol 103 (11) ◽  
pp. 1457-1462 ◽  
Author(s):  
Toyohiko Abe ◽  
Akio Kawai ◽  
Yoshizumi Kajii ◽  
Kazuhiko Shibuya ◽  
Kinichi Obi
Keyword(s):  
Complex Formation ◽  
Solvent Effects ◽  
Ketyl Radical

Solvent effects on complex formation: Cobalt(II)thiourea in ethyl acetate, propanol, propylene carbonate

1983 ◽  
Vol 75 ◽  
pp. 237-240 ◽  
Author(s):  
Ugo Biader Ceipidor ◽  
Vicenzo Carunchio ◽  
Anna Maria Girelli ◽  
Antonella Messina
Keyword(s):  
Complex Formation ◽  
Ethyl Acetate ◽  
Propylene Carbonate ◽  
Solvent Effects

The Photochemically Produced Ketyl of Perfluorobenzophenone: Electron Spin Resonance Studies of Solvent Effects

1973 ◽  
Vol 51 (19) ◽  
pp. 3211-3216 ◽  
Author(s):  
Frederick Peter Sargent ◽  
Marshall Grant Bailey
Keyword(s):  
Electron Spin Resonance ◽  
Equilibrium Constant ◽  
Mole Fraction ◽  
Electron Spin ◽  
Solvent Effects ◽  
Chemical Exchange ◽  
Solvent Molecule ◽  
Solvent Mixtures ◽  
Ketyl Radical ◽  
Spin Resonance

The ketyl radical is formed when solutions of perfluorobenzophenone are photolyzed with u.v. light. The radical was identified by electron spin resonance (e.s.r.) studies of the effects of solvent, temperature, chemical exchange, and deuteration on the spectra. Solvent mixtures of cyclohexane and ethanol gave spectra which were very sensitive to the mole fraction of alcohol in the range 0–1%. An equilibrium constant for solvent molecule exchange has been deduced.

Solvent effects in positronium complex formation and the bubble model

1999 ◽  
Vol 111 (21) ◽  
pp. 9687-9694 ◽  
Author(s):  
Debarshi Gangopadhyay ◽  
Bichitra Nandi Ganguly ◽  
Tapas Mukherjee ◽  
Binayak Dutta-Roy
Keyword(s):  
Complex Formation ◽  
Solvent Effects

Fluorescence of the benzophenone ketyl radical: solvent effects

1989 ◽  
Vol 47 (2) ◽  
pp. 155-165 ◽  
Author(s):  
P. Yankov ◽  
Zh. Nickolov ◽  
V. Zhelyaskov ◽  
I. Petkov
Keyword(s):  
Solvent Effects ◽  
Ketyl Radical
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