Rate Constants for the Reactions of Hydroxyl Radical with Several Alkanes, Cycloalkanes, and Dimethyl Ether

1999 ◽  
Vol 103 (15) ◽  
pp. 2649-2654 ◽  
Author(s):  
W. B. DeMore ◽  
K. D. Bayes
Keyword(s):  
Hydroxyl Radical ◽  
Dimethyl Ether ◽  
Rate Constants

Radiolysis studies on the corrosion inhibitors 1 -hexyn-3-ol, cinnamonitrile, and 1,3-diethyl-2-thiourea

1995 ◽  
Vol 73 (12) ◽  
pp. 2137-2142 ◽  
Author(s):  
A.J. Elliot ◽  
M.P. Chenier ◽  
D.C. Ouellette
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Rate Constant ◽  
Rate Constants ◽  
Corrosion Inhibitors ◽  
Hydrated Electron

In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thiourea ((3.5 ± 0.3) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile and diethylthiourea, the temperature dependence up to 200 °C and 150 °C, respectively, is also reported; (ii) the rate constants for the reaction of the hydroxyl radical with 1-hexyn-3-ol ((5.5 ± 0.5) × 109 dm3 mol−1 s−1 at 20 °C), cinnamonitrile ((9.2 ± 0.3) × 109 dm3 mol−1 s−1 at 21 °C), and diethylthiourea ((8.0 ± 0.8) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile, the temperature dependence up to 200 °C is also reported; (iii) the rate constant for the hydrogen atom reacting with 1-hexyn-3-ol ((4.3 ± 0.4) × 109 dm3 mol−1 s−1 at 20 °C). Keywords: radiolysis, corrosion inhibitors, rate constants.

Reactions of the hydroxyl radical. Part 2.—Determination of absolute rate constants

1965 ◽  
Vol 61 (0) ◽  
pp. 1417-1424 ◽  
Author(s):  
G. E. Adams ◽  
J. W. Boag ◽  
B. D. Michael
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Absolute Rate

Hydroxyl radical rate constants: comparing UV/H2O2 and pulse radiolysis for environmental pollutants

2008 ◽  
Vol 57 (6) ◽  
pp. 391-401 ◽  
Author(s):  
Michael S. Elovitz ◽  
Hilla Shemer ◽  
Julie R. Peller ◽  
K. Vinodgopal ◽  
Mano Sivaganesan ◽  
...  
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Pulse Radiolysis ◽  
Environmental Pollutants

scholarly journals PREDICTION OF REACTION RATE CONSTANTS OF HYDROXYL RADICAL WITH ORGANIC COMPOUNDS

2014 ◽  
Vol 59 (1) ◽  
pp. 2252-2259 ◽  
Author(s):  
ZHEN CHEN ◽  
XINLIANG YU ◽  
XIANWEI HUANG ◽  
SHIHUA ZHANG
Keyword(s):  
Hydroxyl Radical ◽  
Organic Compounds ◽  
Rate Constants ◽  
Reaction Rate ◽  
Reaction Rate Constants

ChemInform Abstract: Rate Constants for the Reactions of the Hydroxyl Radical with Indan, Indene and Styrene

ChemInform ◽  
1990 ◽  
Vol 21 (14) ◽  
Author(s):  
D. L. BAULCH ◽  
I. M. CAMPBELL ◽  
S. M. SAUNDERS ◽  
P. K. K. LOUIE
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants

Rate constants for the reaction of the hydroxyl radical with selected alkanes at 300 K

1978 ◽  
Vol 82 (14) ◽  
pp. 1581-1584 ◽  
Author(s):  
Karen R. Darnall ◽  
Roger Atkinson ◽  
James N. Pitts
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants
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