Pulse Radiolysis Investigations on Acidic Aqueous Solutions of Benzene:  Formation of Radical Cations†

1999 ◽  
Vol 103 (3) ◽  
pp. 379-383 ◽  
Author(s):  
Hari Mohan ◽  
Jai P. Mittal
Keyword(s):  
Aqueous Solutions ◽  
Pulse Radiolysis ◽  
Radical Cations

scholarly journals Spectral Probe for Electron Transfer and Addition Reactions of Azide Radicals with Substituted Quinoxalin-2-Ones in Aqueous Solutions

2021 ◽  
Vol 22 (2) ◽  
pp. 633
Author(s):  
Konrad Skotnicki ◽  
Slawomir Ostrowski ◽  
Jan Cz. Dobrowolski ◽  
Julio R. De la Fuente ◽  
Alvaro Cañete ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Absorption Spectra ◽  
Density Functional ◽  
Reduction Potential ◽  
Biological Significance ◽  
Radical Cations ◽  
Basis Sets ◽  
Double Bonds ◽  
Reduction Potentials

The azide radical (N3●) is one of the most important one-electron oxidants used extensively in radiation chemistry studies involving molecules of biological significance. Generally, it was assumed that N3● reacts in aqueous solutions only by electron transfer. However, there were several reports indicating the possibility of N3● addition in aqueous solutions to organic compounds containing double bonds. The main purpose of this study was to find an experimental approach that allows a clear assignment of the nature of obtained products either to its one-electron oxidation or its addition products. Radiolysis of water provides a convenient source of one-electron oxidizing radicals characterized by a very broad range of reduction potentials. Two inorganic radicals (SO4●−, CO3●−) and Tl2+ ions with the reduction potentials higher, and one radical (SCN)2●− with the reduction potential slightly lower than the reduction potential of N3● were selected as dominant electron-acceptors. Transient absorption spectra formed in their reactions with a series of quinoxalin-2-one derivatives were confronted with absorption spectra formed from reactions of N3● with the same series of compounds. Cases, in which the absorption spectra formed in reactions involving N3● differ from the absorption spectra formed in the reactions involving other one-electron oxidants, strongly indicate that N3● is involved in the other reaction channel such as addition to double bonds. Moreover, it was shown that high-rate constants of reactions of N3● with quinoxalin-2-ones do not ultimately prove that they are electron transfer reactions. The optimized structures of the radical cations (7-R-3-MeQ)●+, radicals (7-R-3-MeQ)● and N3● adducts at the C2 carbon atom in pyrazine moiety and their absorption spectra are reasonably well reproduced by density functional theory quantum mechanics calculations employing the ωB97XD functional combined with the Dunning’s aug-cc-pVTZ correlation-consistent polarized basis sets augmented with diffuse functions.

Pulse radiolysis study of dithio-oxamide in aqueous solutions

2000 ◽  
Vol 26 (4) ◽  
pp. 309-318 ◽  
Author(s):  
G. R. Dey ◽  
D. B. Naik ◽  
P. Dwibedy ◽  
K. Kishore
Keyword(s):  
Aqueous Solutions ◽  
Pulse Radiolysis

ChemInform Abstract: PULSE RADIOLYSIS OF MERCURY(II) CYANIDE IN AQUEOUS SOLUTIONS

1976 ◽  
Vol 7 (7) ◽  
pp. no-no
Author(s):  
SHIN-ICHI FUJITA ◽  
HIDEO HORII ◽  
TOSHIAKI MORI ◽  
SETZUO TANIGUCHI
Keyword(s):  
Aqueous Solutions ◽  
Pulse Radiolysis

scholarly journals Pulse Radiolysis Studies of Solvent Radical Cations in Liquid 1,2-Dichloroethane

1988 ◽  
Vol 61 (9) ◽  
pp. 3055-3059 ◽  
Author(s):  
Takashi Sumiyoshi ◽  
Naoki Sugita ◽  
Kazuyuki Watanabe ◽  
Meiseki Katayama
Keyword(s):  
Pulse Radiolysis ◽  
Radical Cations
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