Dilute Graphite−Sulfates Intercalation Stages Studied by Simultaneous Application of Cyclic Voltammetry, Probe-Beam Deflection, In situ Resistometry, and X-ray Diffraction Techniques

1999 ◽  
Vol 103 (9) ◽  
pp. 1499-1508 ◽  
Author(s):  
M. D. Levi ◽  
E. Levi ◽  
Y. Gofer ◽  
D. Aurbach ◽  
E. Vieil ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Probe Beam ◽  
Beam Deflection ◽  
X Ray Diffraction ◽  
Simultaneous Application ◽  
X Ray

In situ X-ray Investigation of Hydrogen Charging in Thin Film Bimetallic Electrodes

1997 ◽  
Vol 12 (8) ◽  
pp. 2091-2098 ◽  
Author(s):  
Najeh M. Jisrawi ◽  
Harold Wiesmann ◽  
M. W. Ruckman ◽  
T. R. Thurston ◽  
G. Reisfeld ◽  
...  
Keyword(s):  
Thin Film ◽  
Cyclic Voltammetry ◽  
Hydrogen Uptake ◽  
Metallic Films ◽  
X Ray Diffraction ◽  
Cell Potential ◽  
Multilayered Thin Film ◽  
X Ray ◽  
Multilayer Electrode

Hydrogen uptake and discharge by thin metallic films under potentiostatic control was studied using x-ray diffraction at the National Synchroton Light Source (NSLS). The formation of metal-hydrogen phases in Pd, Pd-capped Nb, and Pd/Nb multilayer electrode structures was deduced from x-ray diffraction data and correlated with the cyclic voltammetry (CV) peaks. The x-ray data were also used to construct a plot of the hydrogen concentration as a function of cell potential for a multilayered thin film.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

In-situ Investigation of Bainite Formation with fast X-Ray Diffraction (iXRD)

2017 ◽  
Vol 72 (6) ◽  
pp. 355-364
Author(s):  
A. Kopp ◽  
T. Bernthaler ◽  
D. Schmid ◽  
G. Ketzer-Raichle ◽  
G. Schneider
Keyword(s):  
X Ray Diffraction ◽  
X Ray ◽  
In Situ Investigation

Texture Evolution Under Fast Heating and Cooling Rates of Zirconium Alloys Studied In-Situ by Synchrotron X-Ray Diffraction

2020 ◽  
Author(s):  
Chi-Toan Nguyen ◽  
Alistair Garner ◽  
Javier Romero ◽  
Antoine Ambard ◽  
Michael Preuss ◽  
...  
Keyword(s):  
Texture Evolution ◽  
Zirconium Alloys ◽  
X Ray Diffraction ◽  
Fast Heating ◽  
Cooling Rates ◽  
X Ray ◽  
Heating And Cooling

STRUCTURAL EVOLUTION OF EXCEPTIONALLY IRON-DEFICIENT HEMATITE NANOCRYSTALS AS OBSERVED BY IN SITU SYNCHROTRON X-RAY DIFFRACTION

2019 ◽  
Author(s):  
Si Athena Chen ◽  
◽  
Peter Heaney ◽  
Jeffrey E. Post ◽  
Peter J. Eng ◽  
...  
Keyword(s):  
Structural Evolution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Iron Deficient

Hydrophobic Ferrocene Derivatives as Potential Standards in Electrochemistry

1997 ◽  
Vol 62 (2) ◽  
pp. 185-198 ◽  
Author(s):  
Jaroslav Podlaha ◽  
Petr Štěpnička ◽  
Róbert Gyepes ◽  
Vladimír Mareček ◽  
Alexander Lhotský ◽  
...  
Keyword(s):  
Surface Tension ◽  
Cyclic Voltammetry ◽  
Redox Potential ◽  
Diffusion Coefficients ◽  
Carbon Electrodes ◽  
X Ray Diffraction ◽  
Ferrocene Derivatives ◽  
X Ray ◽  
Special Cases ◽  
As Solubility

Ferrocene (FcH) derivatives monosubstituted by palmitoyl (1), hexadecyl (2), 1-adamantoyl (3) or 1-adamantylmethyl (4) groups were sythesized and characterized by NMR, mass and 57Fe Mossbauer spectroscopy. The structure of 1-adamantoylferrocene was determined by single-crystal X-ray diffraction. Cyclic voltammetry on gold and glass-like carbon electrodes demonstrated that the compounds can serve as electrochemical standards for special cases since their ferrocene/ferricinium redox potential remains stable and reversible, while the properties such as solubility, diffusion coefficients and surface tension are strongly solvent-dependent.

In situ X-ray diffraction techniques as a powerful tool to study battery electrode materials

2002 ◽  
Vol 47 (19) ◽  
pp. 3137-3149 ◽  
Author(s):  
M. Morcrette ◽  
Y. Chabre ◽  
G. Vaughan ◽  
G. Amatucci ◽  
J.-B. Leriche ◽  
...  
Keyword(s):  
Electrode Materials ◽  
X Ray Diffraction ◽  
X Ray ◽  
Battery Electrode

scholarly journals In-Situ Synchrotron X-ray Diffraction Investigation of Microstructural Evolutions During Low-Pressure Carburizing

2021 ◽  
Author(s):  
Ogün Baris Tapar ◽  
Jérémy Epp ◽  
Matthias Steinbacher ◽  
Jens Gibmeier
Keyword(s):  
Carbon Content ◽  
Carbon Diffusion ◽  
Low Pressure ◽  
Carbon Accumulation ◽  
Experimental Chamber ◽  
Carbide Formation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carbon Supply

AbstractAn experimental heat treatment chamber and control system were developed to perform in-situ X-ray diffraction experiments during low-pressure carburizing (LPC) processes. Results from the experimental chamber and industrial furnace were compared, and it was proven that the built system is reliable for LPC experiments. In-situ X-ray diffraction investigations during LPC treatment were conducted at the German Electron Synchrotron Facility in Hamburg Germany. During the boost steps, carbon accumulation and carbide formation was observed at the surface. These accumulation and carbide formation decelerated the further carbon diffusion from atmosphere to the sample. In the early minutes of the diffusion steps, it is observed that cementite content continue to increase although there is no presence of gas. This effect is attributed to the high carbon accumulation at the surface during boost steps which acts as a carbon supply. During quenching, martensite at higher temperature had a lower c/a ratio than later formed ones. This difference is credited to the early transformation of austenite regions having lower carbon content. Also, it was noticed that the final carbon content dissolved in martensite reduced compared to carbon in austenite before quenching. This reduction was attributed to the auto-tempering effect.

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