Gas-Phase Reactions of Nickel and Nickel-Rich Oxide Cluster Anions with Nitric Oxide. 2. The Addition of Nitric Oxide, Oxidation of Nickel Clusters, and the Formation of Nitrogen Oxide Anions

1998 ◽  
Vol 102 (45) ◽  
pp. 8804-8811 ◽  
Author(s):  
W. D. Vann ◽  
R. L. Wagner ◽  
A. W. Castleman
Keyword(s):  
Nitric Oxide ◽  
Nitrogen Oxide ◽  
Gas Phase ◽  
Cluster Anions ◽  
Gas Phase Reactions ◽  
Oxide Cluster ◽  
Nickel Clusters

Gas-phase reactions of nitric oxide with atomic lanthanide cations: Room-temperature kinetics and periodicity in reactivity

2006 ◽  
Vol 249-250 ◽  
pp. 385-391 ◽  
Author(s):  
Voislav Blagojevic ◽  
Eric Flaim ◽  
Michael J.Y. Jarvis ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Room Temperature ◽  
Gas Phase Reactions ◽  
Lanthanide Cations

scholarly journals The HNO− radical anion: A proposed intermediate in diazeniumdiolate synthesis using nitric oxide and alkoxides

2018 ◽  
Vol 25 (1) ◽  
pp. 82-85 ◽  
Author(s):  
Zhe-Chen Wang ◽  
Ya-Ke Li ◽  
Sheng-Gui He ◽  
Veronica M Bierbaum
Keyword(s):  
Nitric Oxide ◽  
Reaction Mechanism ◽  
Gas Phase ◽  
Radical Anion ◽  
Room Temperature ◽  
Hydrogen Transfer ◽  
Gas Phase Reactions ◽  
Ionic Product

The strategy of synthesizing diazeniumdiolates (X–N(O)=NO−) through the coexistence of nitric oxide and alkoxides (RO−) was introduced by Wilhelm Traube 120 years ago. Today, despite the wide use of diazeniumdiolate derivatives to release nitric oxide in the treatment of cancer, the first step of the reaction mechanism for diazeniumdiolate synthesis remains a mystery and is thought to be complex. We have studied the gas-phase reactions of nitric oxide with alkoxides at room temperature. An electron-coupled hydrogen transfer is observed, and the radical anion HNO− is the only ionic product in these reactions. HNO− can further react with nitric oxide to form N2O and HO−.

Nb2BN2− cluster anions reduce four carbon dioxide molecules: reactivity enhancement by ligands

2020 ◽  
Vol 49 (40) ◽  
pp. 14081-14087 ◽  
Author(s):  
Hai-Yan Zhou ◽  
Ming Wang ◽  
Yong-Qi Ding ◽  
Jia-Bi Ma
Keyword(s):  
Mass Spectrometry ◽  
Carbon Dioxide ◽  
Density Functional Theory ◽  
Gas Phase ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Cluster Anions ◽  
Gas Phase Reactions ◽  
Functional Theory ◽  
Flight Mass Spectrometry

The thermal gas-phase reactions of Nb2BN2− cluster anions with carbon dioxide have been explored by using the art of time-of-flight mass spectrometry and density functional theory calculations.

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