Temperature Effects on the Energy Gap Dependence of Charge Recombination Rates of Ion Pairs Produced by Excitation of Charge-Transfer Complexes Adsorbed on Porous Glass

1997 ◽  
Vol 101 (40) ◽  
pp. 7978-7984 ◽  
Author(s):  
Hiroshi Miyasaka ◽  
Shoji Kotani ◽  
Akira Itaya ◽  
Gerd Schweitzer ◽  
Frans C. De Schryver ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Porous Glass ◽  
Temperature Effects ◽  
Energy Gap ◽  
Ion Pairs ◽  
Charge Recombination ◽  
Charge Transfer Complexes ◽  
Recombination Rates

scholarly journals How can infra-red excitation both accelerate and slow charge transfer in the same molecule?

2018 ◽  
Vol 9 (30) ◽  
pp. 6395-6405 ◽  
Author(s):  
Zheng Ma ◽  
Zhiwei Lin ◽  
Candace M. Lawrence ◽  
Igor V. Rubtsov ◽  
Panayiotis Antoniou ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Charge Separation ◽  
Charge Recombination ◽  
Recombination Rates ◽  
Infra Red ◽  
Induced Changes

A UV-IR-Vis 3-pulse study of infra-red induced changes to electron transfer (ET) rates in a donor–bridge–acceptor species finds that charge-separation rates are slowed, while charge-recombination rates are accelerated as a result of IR excitation during the reaction.

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