Role of Zero-Field Splitting Interactions in the NMR Paramagnetic Relaxation Enhancements Produced by Ni(II)(acac)2(H2O)2

Shawn M. Abernathy; Robert R. Sharp

doi:10.1021/jp970254f

Role of Zero-Field Splitting Interactions in the NMR Paramagnetic Relaxation Enhancements Produced by Ni(II)(acac)2(H2O)2

The Journal of Physical Chemistry A ◽

10.1021/jp970254f ◽

1997 ◽

Vol 101 (20) ◽

pp. 3692-3698 ◽

Cited By ~ 13

Author(s):

Shawn M. Abernathy ◽

Robert R. Sharp

Keyword(s):

Paramagnetic Relaxation ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Paramagnetic Relaxation Enhancements

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NMR paramagnetic relaxation due to the S=5∕2 complex, Fe(III)-(tetra-p-sulfonatophenyl)porphyrin: Central role of the tetragonal fourth-order zero-field splitting interaction

The Journal of Chemical Physics ◽

10.1063/1.1886748 ◽

2005 ◽

Vol 122 (18) ◽

pp. 184501 ◽

Cited By ~ 9

Author(s):

Nathaniel Schaefle ◽

Robert Sharp

Keyword(s):

Fourth Order ◽

Paramagnetic Relaxation ◽

Zero Field ◽

Zero Field Splitting ◽

Order Zero ◽

Field Splitting

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The mechanism of paramagnetic NMR relaxation produced by Mn(II): Role of orthorhombic and fourth-order zero field splitting terms

The Journal of Chemical Physics ◽

10.1063/1.2981565 ◽

2008 ◽

Vol 129 (14) ◽

pp. 144307 ◽

Cited By ~ 1

Author(s):

Robert Sharp

Keyword(s):

Fourth Order ◽

Nmr Relaxation ◽

Paramagnetic Nmr ◽

Zero Field ◽

Zero Field Splitting ◽

Order Zero ◽

Field Splitting

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Nuclear magnetic resonance-paramagnetic relaxation enhancements: Influence of spatial quantization of the electron spin when the zero-field splitting energy is larger than the Zeeman energy

The Journal of Chemical Physics ◽

10.1063/1.477003 ◽

1998 ◽

Vol 109 (10) ◽

pp. 4035-4046 ◽

Cited By ~ 21

Author(s):

S. M. Abernathy ◽

J. C. Miller ◽

L. L. Lohr ◽

R. R. Sharp

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Electron Spin ◽

Zero Field ◽

Zeeman Energy ◽

Zero Field Splitting ◽

Field Splitting ◽

Spatial Quantization ◽

Paramagnetic Relaxation Enhancements ◽

Splitting Energy

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Determination of the role of vibrational coupling in the temperature dependence of the zero-field splitting from the isotope effect

Molecular Physics ◽

10.1080/00268977700102461 ◽

1977 ◽

Vol 34 (4) ◽

pp. 1195-1197 ◽

Cited By ~ 5

Author(s):

F.J. Owens

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Zero Field ◽

Zero Field Splitting ◽

Vibrational Coupling ◽

Field Splitting

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NMR Paramagnetic Relaxation Enhancement: Measurement of an Axial/EquatorialT1Ratio forS= 1 in the Zero-Field Splitting Limit

The Journal of Physical Chemistry A ◽

10.1021/jp994114c ◽

2000 ◽

Vol 104 (21) ◽

pp. 4839-4845 ◽

Cited By ~ 12

Author(s):

Jeremy Miller ◽

Shawn Abernathy ◽

Robert Sharp

Keyword(s):

Paramagnetic Relaxation ◽

Paramagnetic Relaxation Enhancement ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Effect of zero field splitting interactions on the paramagnetic relaxation enhancement of nuclear spin relaxation rates in solution

The Journal of Chemical Physics ◽

10.1063/1.464255 ◽

1993 ◽

Vol 98 (2) ◽

pp. 912-921 ◽

Cited By ~ 27

Author(s):

Robert R. Sharp

Keyword(s):

Spin Relaxation ◽

Nuclear Spin ◽

Paramagnetic Relaxation ◽

Paramagnetic Relaxation Enhancement ◽

Nuclear Spin Relaxation ◽

Zero Field ◽

Relaxation Rates ◽

Zero Field Splitting ◽

Field Splitting

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Multifrequency electron paramagnetic resonance and theoretical studies of a Mn(II) (S=5/2) complex: The role of geometrical elements on the Zero Field Splitting parameters

Polyhedron ◽

10.1016/j.poly.2009.07.004 ◽

2009 ◽

Vol 28 (15) ◽

pp. 3257-3264 ◽

Cited By ~ 9

Author(s):

Theodora D. Tzima ◽

George Sioros ◽

Carole Duboc ◽

Demetra Kovala-Demertzi ◽

Vasilios S. Melissas ◽

...

Keyword(s):

Electron Paramagnetic Resonance ◽

Zero Field ◽

Theoretical Studies ◽

Zero Field Splitting ◽

Paramagnetic Resonance ◽

Field Splitting ◽

Electron Paramagnetic

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Correlating the axial Zero Field Splitting with the slow magnetic relaxation in GdIII SIMs

Chemical Communications ◽

10.1039/d0cc07474h ◽

2021 ◽

Author(s):

Júlia Mayans ◽

Albert Escuer

Keyword(s):

Magnetic Relaxation ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Slow Magnetic Relaxation

A possible relation between the value of the axial Zero Field Splitting and the occurrence of field-induced slow magnetic relaxation has been established for a new gadolinium(iii) compound.

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VERIFICATION OF ZERO-FIELD SPLITTING THEORY FOR SPIN S = 2 IONS IN MAGNETIC INSULATORS

Le Journal de Physique Colloques ◽

10.1051/jphyscol:19888424 ◽

1988 ◽

Vol 49 (C8) ◽

pp. C8-931-C8-932 ◽

Cited By ~ 4

Author(s):

Czesław Rudowicz

Keyword(s):

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Magnetic Insulators

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The role of zero-field splitting and π-stacking interaction of different nitrogen-donor ligands on the optical properties of luminescent rhenium tricarbonyl complexes

New Journal of Chemistry ◽

10.1039/d1nj01544c ◽

2021 ◽

Author(s):

Plinio Cantero-López ◽

Yoan Hidalgo-Rosa ◽

Zoraida Sandoval-Olivares ◽

Julián Santoyo-Flores ◽

Pablo Mella ◽

...

Keyword(s):

Excited States ◽

Coordination Compounds ◽

Donor Ligands ◽

Zero Field ◽

Zero Field Splitting ◽

Nitrogen Donor Ligands ◽

Nitrogen Donor ◽

Π Stacking Interaction ◽

Rhenium Tricarbonyl

Rhenium tricarbonyl complexes are one of the most important classes of coordination compounds in inorganic chemistry. Exploring their luminescent excited states, lowest singlet (S1), and the lowest triplet (T1), is...

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