Coexistence Curve of the Ionic Binary Mixture Ethylammonium Nitrate−n-Octanol:  Critical Properties

1997 ◽  
Vol 101 (12) ◽  
pp. 2164-2173 ◽  
Author(s):  
M. Bonetti ◽  
A. Oleinikova ◽  
C. Bervillier
Keyword(s):  
Binary Mixture ◽  
Coexistence Curve ◽  
Critical Properties ◽  
Nitrate N ◽  
Ethylammonium Nitrate

Structure of a Binary Mixture of Ethylammonium Nitrate and Methanol

2015 ◽  
Vol 44 (3-4) ◽  
pp. 669-685 ◽  
Author(s):  
Olga Russina ◽  
Alessandro Mariani ◽  
Ruggero Caminiti ◽  
Alessandro Triolo
Keyword(s):  
Binary Mixture ◽  
Ethylammonium Nitrate

scholarly journals Prediction of the Roles of Critical Properties for Pure and Binary Mixture Working Fluid in Rankine Cycle Performances

2015 ◽  
Vol 66 ◽  
pp. 57-60 ◽  
Author(s):  
Tianyou Wang ◽  
Yajun Zhang ◽  
Pengfei Wang ◽  
Zhijun Peng ◽  
Gequn Shu
Keyword(s):  
Binary Mixture ◽  
Rankine Cycle ◽  
Working Fluid ◽  
Critical Properties

scholarly journals Statistic-Driven Proton Transfer Affecting Nanoscopic Organization in an Ethylammonium Nitrate Ionic Liquid and 1,4-Diaminobutane Binary Mixture: A Steamy Pizza Model

Symmetry ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1425 ◽  
Author(s):  
Alessandro Mariani ◽  
Matteo Bonomo ◽  
Stefano Passerini
Keyword(s):  
Binary Mixture ◽  
Ternary Mixture ◽  
Chemical Properties ◽  
Significant Excess ◽  
Similar Chemical ◽  
Neutral Compounds ◽  
Ethylammonium Nitrate ◽  
One Year ◽  
Over Time ◽  
Basic Strength

Herein, we report on the theoretical and experimental investigation of the chemical equilibrium in a Ethylammonium Nitrate (EAN)/1,4-Diaminobutane (DAB) binary mixture displaying a significant excess of the latter component (namely, a 1:9 mole ratio). Both the neutral compounds, i.e., ethylamine (EtNH2) and DAB, present very similar chemical properties, especially concerning their basic strength, resulting in a continuous jump of the proton from the ethylammonium to the diamine (and vice-versa). Due to the significant excess of DAB, the proton is (statistically) expected to be bound to one of its nitrogen atoms, leading to the formation of a new (ternary) mixture containing DAB (ca. 80%), ethylamine (ca. 10%) and 4-amino-1-butylammonium nitrate (ABAN, ca. 10%). This is probed by means of SAXS measurements, showing LqE (low q excess) that increases over time. This feature tends to stabilize after approximately one day. When the measurement is repeated after one year, the LqE feature shows an increased intensity. Based on the results of our simulations, we suggest that this phenomenon is likely due to partial ethylamine evaporation, pushing the equilibrium toward the formation of ABAN.

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