Spectral and Photophysical Properties of Ethylene-Bridged Side-to-Side Porphyrin Dimers. 2. Femtosecond Transient Absorption and Picosecond Fluorescence Study oftrans-1,2-Bis(meso-octaethylporphyrinyl)ethene

1996 ◽  
Vol 100 (32) ◽  
pp. 13867-13873 ◽  
Author(s):  
Mirianas Chachisvilis ◽  
Vladimir S. Chirvony ◽  
Alexander M. Shulga ◽  
Bruno Källebring ◽  
Sven Larsson ◽  
...  
Keyword(s):  
Transient Absorption ◽  
Photophysical Properties ◽  
Fluorescence Study ◽  
Femtosecond Transient Absorption ◽  
Porphyrin Dimers

scholarly journals Femtosecond Transient Absorption Microspectroscopy of Benzil Confined Into a Single Bead of Porous Glass

1996 ◽  
Vol 16 (3) ◽  
pp. 197-206 ◽  
Author(s):  
Christopher F. Porter ◽  
Naoto Tamai ◽  
Hiroshi Masuhara
Keyword(s):  
Pore Diameter ◽  
Transient Absorption ◽  
Polar Solvent ◽  
Photophysical Properties ◽  
Free Solution ◽  
Average Pore ◽  
Porous Glasses ◽  
Planar Form ◽  
Femtosecond Transient Absorption ◽  
Single Bead

The photophysical properties of benzil dissolved in free solution and in solution confined into a single bead of porous glasses (size < 100 μm) were investigated by femtosecond transient absorption microspectroscopy. In nonpolar solvent, cyclohexane, the rate of conformational change from the skewed to the near trans-planar form was reduced from 2.2 × 1012s-1 in free solution to 9.1 × 1011s-1 in porous glasses with an average pore diameter of 26 nm. In polar solvent, DMF, however, there was little difference between the two systems.

Probing the Structural Features and the Micro-heterogeneity of Various Deep Eutectic Solvents and their Water Dilutions by the Photophysical Behaviour of Two Fluorophores

2020 ◽  
Author(s):  
Matteo Tiecco ◽  
Irene Di Guida ◽  
Pier Luigi Gentili ◽  
Raimondo Germani ◽  
Carmela Bonaccorso ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transient Absorption ◽  
Photophysical Properties ◽  
Deep Eutectic Solvents ◽  
Structural Features ◽  
Solvation Dynamics ◽  
Structured Systems ◽  
Reduced Viscosity ◽  
Bond Network ◽  
Fluorescent Molecules

<div><div><div><p>The structural features of a series of diverse Deep Eutectic Solvents (DESs) have been investigated and characterized by means of two fluorescent probes. The spectral and photophysical properties of the latter are strictly dependent on the experienced environment, so that they can provide insights into the polarity, viscosity, hydrogen-bond network, and micro-heterogeneity of the various DESs.</p><p>In fact, the investigated DESs exhibit a variety of properties with regards to their hydrophilicity, acidity, and hydrogen-bond ability, and these details were deeply probed by the two fluorescent molecules. The effect of the addition of water, which is a key strategy for tuning the properties of these structured systems, was also tested. In particular, the excited state dynamics of the probes, measured by femtosecond-resolved transient absorption, proved instrumental in understanding the changes in the structural properties of the DESs, namely reduced viscosity and enhanced heterogeneity, as the water percentage increases. Differences between the various DESs in terms of both local microheterogeneity and bulk viscosity also emerged from the peculiar multi-exponential solvation dynamics undergone by the excited states of the probes.</p></div></div></div>

Probing the Structural Features and the Micro-heterogeneity of Various Deep Eutectic Solvents and their Water Dilutions by the Photophysical Behaviour of Two Fluorophores

2020 ◽  
Author(s):  
Matteo Tiecco ◽  
Irene Di Guida ◽  
Pier Luigi Gentili ◽  
Raimondo Germani ◽  
Carmela Bonaccorso ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transient Absorption ◽  
Photophysical Properties ◽  
Deep Eutectic Solvents ◽  
Structural Features ◽  
Solvation Dynamics ◽  
Structured Systems ◽  
Reduced Viscosity ◽  
Bond Network ◽  
Fluorescent Molecules

<div><div><div><p>The structural features of a series of diverse Deep Eutectic Solvents (DESs) have been investigated and characterized by means of two fluorescent probes. The spectral and photophysical properties of the latter are strictly dependent on the experienced environment, so that they can provide insights into the polarity, viscosity, hydrogen-bond network, and micro-heterogeneity of the various DESs.</p><p>In fact, the investigated DESs exhibit a variety of properties with regards to their hydrophilicity, acidity, and hydrogen-bond ability, and these details were deeply probed by the two fluorescent molecules. The effect of the addition of water, which is a key strategy for tuning the properties of these structured systems, was also tested. In particular, the excited state dynamics of the probes, measured by femtosecond-resolved transient absorption, proved instrumental in understanding the changes in the structural properties of the DESs, namely reduced viscosity and enhanced heterogeneity, as the water percentage increases. Differences between the various DESs in terms of both local microheterogeneity and bulk viscosity also emerged from the peculiar multi-exponential solvation dynamics undergone by the excited states of the probes.</p></div></div></div>

scholarly journals Femtosecond Transient Absorption Studies of Two Novel Energetic Tetrazole Derivatives

2021 ◽  
pp. 100016
Author(s):  
Naga Krishnakanth Katturi ◽  
Chinmoy Biswas ◽  
Nagarjuna Kommu ◽  
Sai Santosh Kumar Raavi ◽  
Venugopal Rao Soma
Keyword(s):  
Transient Absorption ◽  
Femtosecond Transient Absorption ◽  
Absorption Studies ◽  
Tetrazole Derivatives

scholarly journals Ultrafast nonequilibrium dynamic process of separate electron and hole during exciton formation in few-layer tungsten disulfide

2021 ◽  
Author(s):  
Junjie Chen ◽  
Sen Guo ◽  
Dabin Lin ◽  
Zhaogang Nie ◽  
Chung-Che Huang ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Dynamic Process ◽  
Formation Process ◽  
Transient Absorption ◽  
Tungsten Disulfide ◽  
Transient Absorption Spectroscopy ◽  
Femtosecond Transient Absorption ◽  
Nonequilibrium Dynamic ◽  
Femtosecond Transient Absorption Spectroscopy ◽  
Separate Electron

Femtosecond transient absorption spectroscopy has been employed to unravel separate initial nonequilibrium dynamic process of photo-injected electrons and holes during the formation process of the lowest excitons at the K-valley...

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