Solvent Dependence of the Kinetic Isotope Effect in the Reaction of Ascorbate with the 2,2,6,6-Tetramethylpiperidine-1-oxyl Radical: Tunnelling in a Small Molecule Reaction

Ivana Sajenko; Viktor Pilepić; Cvijeta Jakobušić Brala; Stanko Uršić

doi:10.1021/jp911086n

Solvent Dependence of the Kinetic Isotope Effect in the Reaction of Ascorbate with the 2,2,6,6-Tetramethylpiperidine-1-oxyl Radical: Tunnelling in a Small Molecule Reaction

The Journal of Physical Chemistry A ◽

10.1021/jp911086n ◽

2010 ◽

Vol 114 (10) ◽

pp. 3423-3430 ◽

Cited By ~ 15

Author(s):

Ivana Sajenko ◽

Viktor Pilepić ◽

Cvijeta Jakobušić Brala ◽

Stanko Uršić

Keyword(s):

Isotope Effect ◽

Small Molecule ◽

Kinetic Isotope Effect ◽

Molecule Reaction ◽

Kinetic Isotope ◽

Solvent Dependence

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Solvent Dependence of Enantioselectivity for a Base-Catalyzed 1,3-Hydron Transfer Reaction. A Kinetic Isotope Effect and NMR Spectroscopic Study

The Journal of Organic Chemistry ◽

10.1021/jo00110a046 ◽

1995 ◽

Vol 60 (5) ◽

pp. 1356-1364 ◽

Cited By ~ 18

Author(s):

Marie Aune ◽

Adolf Gogoll ◽

Olle Matsson

Keyword(s):

Spectroscopic Study ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Transfer Reaction ◽

Kinetic Isotope ◽

Solvent Dependence

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Solvent dependence of the carbon kinetic isotope effect on the decarboxylation of 4-pyridylacetic acid. A model for enzymatic decarboxylations

Journal of the American Chemical Society ◽

10.1021/ja00276a031 ◽

1986 ◽

Vol 108 (16) ◽

pp. 4896-4899 ◽

Cited By ~ 18

Author(s):

John F. Marlier ◽

Marion H. O'Leary

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

Solvent Dependence

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Theory of proton-transfer reactions. On the solvent dependence of the kinetic isotope effect

Chemical Physics ◽

10.1016/0301-0104(84)87005-6 ◽

1984 ◽

Vol 88 (3) ◽

pp. 391-397 ◽

Cited By ~ 4

Author(s):

J. Sühnel ◽

K. Gustav

Keyword(s):

Proton Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Solvent Dependence ◽

Proton Transfer Reactions

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Solvent dependence of the primary deuterium kinetic isotope effect in the sodium hydroxide-catalysed E2 elimination of hydrogen bromide from p-acetyl- and p-nitro-phenethyl bromide

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29750001218 ◽

1975 ◽

pp. 1218 ◽

Cited By ~ 3

Author(s):

Leonard F. Blackwell ◽

John L. Woodhead

Keyword(s):

Sodium Hydroxide ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydrogen Bromide ◽

Kinetic Isotope ◽

Solvent Dependence

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ChemInform Abstract: Solvent Dependence of the Carbon Kinetic Isotope Effect on the Decarboxylation of 4-Pyridylacetic Acid.

Chemischer Informationsdienst ◽

10.1002/chin.198650154 ◽

1986 ◽

Vol 17 (50) ◽

Author(s):

J. F. MARLIER ◽

M. H. O'LEARY

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

Solvent Dependence

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ChemInform Abstract: SOLVENT DEPENDENCE OF THE PRIMARY DEUTERIUM KINETIC ISOTOPE EFFECT IN THE SODIUM HYDROXIDE-CATALYSED E2 ELIMINATION OF HYDROGEN BROMIDE FROM P-ACETYL- AND P-NITRO-PHENETHYL BROMIDE

Chemischer Informationsdienst ◽

10.1002/chin.197548128 ◽

1975 ◽

Vol 6 (48) ◽

pp. no-no

Author(s):

LEONARD F. BLACKWELL ◽

JOHN L. WOODHEAD

Keyword(s):

Sodium Hydroxide ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydrogen Bromide ◽

Kinetic Isotope ◽

Solvent Dependence

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Faculty Opinions recommendation of Measurement of (carbon) kinetic isotope effect by Rayleigh fractionation using membrane inlet mass spectrometry for CO2-consuming reactions.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1158244.618371 ◽

2009 ◽

Author(s):

Edward Laws

Keyword(s):

Mass Spectrometry ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Membrane Inlet Mass Spectrometry ◽

Rayleigh Fractionation ◽

Kinetic Isotope

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Understanding the Large Kinetic Isotope Effect of Hydrogen Tunneling in Condensed Phases by Using Double-Well Model Systems

The Journal of Physical Chemistry B ◽

10.1021/acs.jpcb.1c02851 ◽

2021 ◽

Author(s):

Yanying Liu ◽

Yaming Yan ◽

Tao Xing ◽

Qiang Shi

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Model Systems ◽

Condensed Phases ◽

Hydrogen Tunneling ◽

Kinetic Isotope ◽

Well Model

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Mechanistic Implication of the pH Effect and H/D Kinetic Isotope Effect on HCOOH/HCOO– Oxidation at Pt Electrodes: A Study by Computer Simulation

ACS Catalysis ◽

10.1021/acscatal.1c01035 ◽

2021 ◽

pp. 6920-6930

Author(s):

Meng-Ke Zhang ◽

Wei Chen ◽

Zhen Wei ◽

Mian-Le Xu ◽

ZhengDa He ◽

...

Keyword(s):

Computer Simulation ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Ph Effect ◽

Kinetic Isotope ◽

Pt Electrodes

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Quantum electrocatalysts: theoretical picture, electrochemical kinetic isotope effect analysis, and conjecture to understand microscopic mechanisms

Physical Chemistry Chemical Physics ◽

10.1039/d0cp01052a ◽

2020 ◽

Vol 22 (20) ◽

pp. 11219-11243 ◽

Cited By ~ 5

Author(s):

Ken Sakaushi

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Effect Analysis ◽

Kinetic Isotope

The fundamental aspects of quantum electrocatalysts are discussed together with the newly developed electrochemical kinetic isotope effect (EC-KIE) approach.

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