Organometallic Oligomer Resolved by Radial Distribution Function of X-ray Diffraction Analysis

2010 ◽  
Vol 114 (7) ◽  
pp. 2359-2364 ◽  
Author(s):  
Roberto Matassa ◽  
Marilena Carbone ◽  
Ilaria Fratoddi ◽  
Ruggero Caminiti
1981 ◽  
Vol 14 (6) ◽  
pp. 417-420 ◽  
Author(s):  
E. Paredes ◽  
P. Colonomos

As a model for the internal structure of polymer crazes, a system of parallel cylinders with liquid-like order is proposed. X-ray diffraction curves were calculated for such a system with Monte Carlo data for the radial distribution function of the two-dimensional hard-disk fluid at different packing densities. A comparison is made between the present calculations and experimental results of crazed polycarbonate showing a very good agreement. A way of evaluating the average craze fibril diameter with the calculations is also discussed.


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