Lanthanide-Doped Layered Double Hydroxides Intercalated with Sensitizing Anions: Efficient Energy Transfer between Host and Guest Layers

2009 ◽  
Vol 113 (39) ◽  
pp. 17206-17214 ◽  
Author(s):  
Poernomo Gunawan ◽  
Rong Xu
Keyword(s):  
Energy Transfer ◽  
Layered Double Hydroxides ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Double Hydroxides

scholarly journals Luminescent Layered Double Hydroxides Intercalated with an Anionic Photosensitizer via the Memory Effect

Crystals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 153 ◽  
Author(s):  
Alexandre Teixeira ◽  
Alysson Morais ◽  
Ivan Silva ◽  
Eric Breynaert ◽  
Danilo Mustafa
Keyword(s):  
Aqueous Solution ◽  
Memory Effect ◽  
Layered Double Hydroxides ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Calcination Temperatures ◽  
Anionic Species ◽  
Benzenetricarboxylic Acid ◽  
Double Hydroxides ◽  
Rehydration Process

Layered double hydroxides (LDHs) containing Eu3+ activators were synthesized by coprecipitation of Zn2+, Al3+, and Eu3+ in alkaline NO3−-rich aqueous solution. Upon calcination, these materials transform into a crystalline ZnO solid solution containing Al and Eu. For suitably low calcination temperatures, this phase can be restored to LDH by rehydration in water, a feature known as the memory effect. During rehydration of an LDH, new anionic species can be intercalated and functionalized, obtaining desired physicochemical properties. This work explores the memory effect as a route to produce luminescent LDHs intercalated with 1,3,5-benzenetricarboxylic acid (BTC), a known anionic photosensitizer for Eu3+. Time-dependent hydration of calcined LDHs in a BTC-rich aqueous solution resulted in the recovery of the lamellar phase and in the intercalation with BTC. The interaction of this photosensitizer with Eu3+ in the recovered hydroxide layers gave rise to efficient energy transfer from the BTC antennae to the Eu3+ ions, providing a useful tool to monitor the rehydration process of the calcined LDHs.

Efficient artificial light-harvesting systems based on aggregation-induced emission constructed in supramolecular gels

Soft Matter ◽  
2021 ◽  
Author(s):  
Xinxian Ma ◽  
bo qiao ◽  
Jinlong Yue ◽  
JingJing Yu ◽  
yutao geng ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Rhodamine B ◽  
Fluorescent Dyes ◽  
Light Harvesting ◽  
Artificial Light ◽  
Efficient Energy Transfer ◽  
Aggregation Induced Emission ◽  
Efficient Energy ◽  
Harvesting Systems ◽  
Acyl Hydrazone

Based on a new designed acyl hydrazone gelator (G2), we developed an efficient energy transfer supramolecular organogel in glycol with two different hydrophobic fluorescent dyes rhodamine B (RhB) and acridine...

Efficient Energy Transfer in Mixed Columnar Stacks of Hydrogen-Bonded Oligo(p-phenylene vinylene)s in Solution

2004 ◽  
Vol 43 (15) ◽  
pp. 1976-1979 ◽  
Author(s):  
Freek J. M. Hoeben ◽  
Laura M. Herz ◽  
Clément Daniel ◽  
Pascal Jonkheijm ◽  
Albertus P. H. J. Schenning ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Phenylene Vinylene ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Hydrogen Bonded

Hybrid organic/inorganic semiconductor nanostructures with highly efficient energy transfer

2012 ◽  
Vol 22 (21) ◽  
pp. 10816 ◽  
Author(s):  
Diana Savateeva ◽  
Dzmitry Melnikau ◽  
Vladimir Lesnyak ◽  
Nikolai Gaponik ◽  
Yury P. Rakovich
Keyword(s):  
Energy Transfer ◽  
Semiconductor Nanostructures ◽  
Efficient Energy Transfer ◽  
Efficient Energy ◽  
Highly Efficient ◽  
Inorganic Semiconductor

Photochemistry of Anthracene-Appended Cobalt(III) Cyclam Complexes

2008 ◽  
Vol 61 (8) ◽  
pp. 585 ◽  
Author(s):  
Simon Boyd ◽  
Kenneth P. Ghiggino ◽  
W. David McFadyen
Keyword(s):  
Energy Transfer ◽  
Ligand Exchange ◽  
Large Excess ◽  
Release Process ◽  
Efficient Energy Transfer ◽  
Ligand Exchange Reaction ◽  
Efficient Energy ◽  
Exchange Processes ◽  
Cyclam Complexes ◽  
In Cis

The photochemistry of two anthracene-appended cobalt(iii) cyclam complexes is explored with a view to demonstrate a photoactivated ligand release process. The ligand exchange processes that occur in the complexes cis-[CoL(NO2)(ONO)]+ and trans-[CoL(NO2)(ONO)]+ in which L = 6-(anthracen-9-ylmethyl)-1,4,8,11-tetraazacyclotetradecane were monitored upon illumination of the anthracenyl chromophore at 360 nm in the presence of a large excess of thiocyanate. The trans-[CoL(NO2)(ONO)]+ complex underwent a ligand exchange reaction in the absence of light and displayed an enhancement of the reaction upon illumination. In contrast the cis-[CoL(NO2)(ONO)]+ complex was stable in the dark but displayed a significant quantum yield of photoactivated ligand release (Φ = 0.19). It is proposed that in cis-[CoL(NO2)(ONO)]+ the photoexcited anthracenyl chromophore undergoes efficient energy transfer to the cobalt(iii) cyclam before ligand exchange. Complexes based on the anthracenylcyclam–cobalt(iii) framework may be potentially useful candidates as photoactivated ligand release systems.

Sign in / Sign up

Export Citation Format

Share Document