Interfacial Behavior of Perchlorate versus Chloride Ions in Aqueous Solutions

2009 ◽  
Vol 113 (48) ◽  
pp. 15843-15850 ◽  
Author(s):  
Marcel D. Baer ◽  
I-Feng William Kuo ◽  
Hendrik Bluhm ◽  
Sutapa Ghosal
Keyword(s):  
Aqueous Solutions ◽  
Chloride Ions ◽  
Interfacial Behavior

Association of benflurone in aqueous solutions studied by measuring the activity of chloride ions

1986 ◽  
Vol 51 (11) ◽  
pp. 2437-2443
Author(s):  
František Kopecký ◽  
Mária Vojteková ◽  
Milan Pešák
Keyword(s):  
Aqueous Solutions ◽  
Chloride Ions ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Measured Range

The conventional activity of chloride ions was measured by an ion-selective electrode at 25 °C in aqueous solutions of benflurone, i.e. 5-(2-(N,N-dimethylamino)ethoxy)-7-oxo-7H-benzo(c)fluorene hydrochloride, without or with additions of KCl. These results suggest a gradual association of benflurone; the formation of a hetero-associate, (BH+)2Cl-, followed by higher associates was evaluated in the measured range up to 0.1 mol l-1.

Sorption of Cadmium and Lead by Chelating Ion Exchangers Ostsorb OXIN, Ostsorb DETA, and Ostsorb DTTA

1994 ◽  
Vol 59 (6) ◽  
pp. 1311-1318 ◽  
Author(s):  
Ladislav Svoboda ◽  
Petr Vořechovský
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Sodium Perchlorate ◽  
Exchange Capacity ◽  
Chloride Ions ◽  
Point Of View ◽  
Alkaline Media ◽  
Ion Exchangers ◽  
Acidic Media ◽  
Cadmium And Lead

The properties of cellulose chelating ion exchangers Ostsorb have been studied in the sorption of cadmium and lead from aqueous solutions. The Cd(II) and Pb(II) ions are trapped by the Ostsorb OXIN and Ostsorb DETA ion exchangers most effectively in neutral and alkaline media but at these conditions formation of stable hydrolytic products of both metals competes with the exchange equilibria. From this point of view, Ostsorb DTTA appears to be a more suitable sorbent since it traps the Pb(II) and Cd(II) ions in acidic media already. Chloride ions interfere with the sorption of the two metals by Ostsorb DTTA whereas the ionic strength adjusted by the addition of sodium perchlorate does not affect the exchange capacity of this ion exchanger.

Effect of Chloride Ions on the Hydrolysis of Trivalent Lanthanum, Praseodymium and Lutetium in Aqueous Solutions of 2 M Ionic Strength

2005 ◽  
Vol 34 (4) ◽  
pp. 427-441 ◽  
Author(s):  
H. López-González ◽  
M. Solache-Ríos ◽  
M. Jiménez-Reyes ◽  
J. J. Ramírez-García ◽  
A. Rojas-Hernández
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Chloride Ions ◽  
Hydrolysis Of

Photochlorination of aniline in Fe3+-containing saline water under simulated solar light irradiation

2012 ◽  
Vol 9 (6) ◽  
pp. 558 ◽  
Author(s):  
Lei Wu ◽  
Xuefeng Hu
Keyword(s):  
Aqueous Solutions ◽  
Aromatic Amines ◽  
Saline Water ◽  
Chloride Ions ◽  
Light Irradiation ◽  
Solar Light ◽  
Natural Seawater ◽  
Simulated Solar Light ◽  
Solar Light Irradiation ◽  
Transformation Pathway

Environmental context Aromatic amines are widely used chemicals, which show enhanced toxicity and longer environmental persistence when halogenated. We investigated the chlorination of aniline in seawater and in natural aqueous solutions containing Fe3+ and Cl–, under simulated sunlight irradiation. The results increase our understanding of the transformation pathway of typical nitrogen-containing aromatic contaminants in the environment. Abstract Photochlorination of aniline was observed in aqueous solutions containing dissolved FeIII and chloride ions under simulated solar light irradiation. Effects of O2, Cl–, Fe3+ and pH on the formation of chloroanilines (CAs) were investigated. para-chloroaniline (4CA) was identified as the main chlorinated product. The formation of 4CA is enhanced with increased concentrations of Cl– or Fe3+, and decreased pH, whereas oxygen plays a negligible role in the process. The results indicate that, Cl• is formed mainly by the photodissociation of FeCl2+–FeCl2+ complexes, and reacts with Cl– to produce Cl2•–. Aniline is then oxidised by Cl2•– into an anilino radical cation, which further reacts with Cl2•– to generate CAs. The photochlorination of aniline in natural seawater was also observed. Other phototransformation products of aniline were detected and a transformation pathway was proposed. This work provides evidence for the photochemical chlorination path of aniline-based aromatic amines in aqueous solutions.

Corrosion of Medium Carbon Steel in Aqueous Solutions Containing Fluoride Ions at 300 C

CORROSION ◽  
1984 ◽  
Vol 40 (4) ◽  
pp. 186-189 ◽  
Author(s):  
P. Mayer ◽  
A. V. Manolescu ◽  
E. M. Rasile
Keyword(s):  
Carbon Steel ◽  
Aqueous Solutions ◽  
Medium Carbon Steel ◽  
Chloride Ions ◽  
Fluoride Ions ◽  
Boiler Water ◽  
Internal Corrosion ◽  
Medium Carbon ◽  
Fabrication Defects ◽  
Parallel Tests

Abstract The accelerated internal corrosion in boiler evaporators results from an unfavorable coincidence of adverse thermohydraulic conditions, boiler water contamination, and fabrication defects. Boiler tube material (medium carbon steel, Type SA210) was exposed in static autoclaves to aqueous solutions of HF, FeF3, and NiF2 at 300 C, and the rate of attack and morphology of the resulting scales were established. For comparison, parallel tests were conducted in aqueous solutions containing chloride ions. This work establishes the role played by fluoride contamination of the boiler water.

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