New Type of Dual Solid-State Thermochromism: Modulation of Intramolecular Charge Transfer by Intermolecular π−π Interactions, Kinetic Trapping of the Aci-Nitro Group, and Reversible Molecular Locking

2009 ◽  
Vol 113 (42) ◽  
pp. 11354-11366 ◽  
Author(s):  
Panče Naumov ◽  
Sang Cheol Lee ◽  
Nobuo Ishizawa ◽  
Young Gyu Jeong ◽  
Ihn Hee Chung ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Nitro Group ◽  
Intramolecular Charge Transfer ◽  
Π Interactions ◽  
New Type ◽  
Kinetic Trapping

Solid-State Emission of the Anthracene-o-Carborane Dyad from the Twisted-Intramolecular Charge Transfer in the Crystalline State

2016 ◽  
Vol 129 (1) ◽  
pp. 260-265 ◽  
Author(s):  
Hirofumi Naito ◽  
Kenta Nishino ◽  
Yasuhiro Morisaki ◽  
Kazuo Tanaka ◽  
Yoshiki Chujo
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Crystalline State ◽  
Intramolecular Charge Transfer ◽  
Twisted Intramolecular Charge Transfer

Intramolecular charge-transfer fluorescence of 1-phenyl-4-[(4-cyano-1-naphthyl)methylene]piperidine (fluoroprobe) as a sensor for phase transitions in the solid state

2010 ◽  
Vol 111 (12) ◽  
pp. 507-510 ◽  
Author(s):  
Leonardus W. Jenneskens ◽  
Herman J. Verhey ◽  
Hendrik J. van Ramesdonk ◽  
Jan W. Verhoeven ◽  
Kees F. van Malssen ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Charge Transfer ◽  
Solid State ◽  
Intramolecular Charge Transfer

scholarly journals Crystal Structures and Optical Properties of Two Novel 1,3,5-Trisubstituted Pyrazoline Derivatives

Crystals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 467
Author(s):  
Qi Feng ◽  
Wenhui Huan ◽  
Jiali Wang ◽  
Jiadan Lu ◽  
Guowang Diao ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
Solid State ◽  
Physical Properties ◽  
Intramolecular Charge Transfer ◽  
Solvent Polarity ◽  
Dihedral Angles ◽  
Polar Solvents ◽  
X Ray ◽  
X Ray Crystallography

Two novel 1,3,5-trisubstituted pyrazoline derivatives—1-acetyl-3-(4-methoxyphenyl)-5-(6-methoxy-2-naphthyl)-pyrazoline (2a) and 1-(4-nitrophenyl)-3-(4-methoxyphenyl)-5-(6-methoxy-2-naphtyl)-pyrazoline (2b)—were synthesized and their structures were determined by single crystal X-ray crystallography. Both of the two crystals exhibit twisted structures due to the large dihedral angles between the pyrazolinyl ring and the aromatic ring at the 5-position (88.09° for 2a and 71.26° for 2b). The optical–physical properties of the two compounds were investigated. The fluorescent emission of 2b arises from the 1,3-disubstituted pyrazoline chromophores and exhibits a red shift in polar solvents and solid-state, which could be attributed to photo-induced intramolecular charge transfer (ICT) from N1 to C3 in the pyrazoline moiety and the intermolecular interactions within the crystal. The fluorescent emissions of 2a (λmax 358–364 nm) in solvents and solid-state both come from 6-methoxy-2-naphthyl chromophores, which are fairly insensitive to the solvent polarity.

scholarly journals Intramolecular charge transfer induced emission from triphenylamine-o-carborane dyads

RSC Advances ◽  
2017 ◽  
Vol 7 (56) ◽  
pp. 35543-35548 ◽  
Author(s):  
Yi Wan ◽  
Junfeng Li ◽  
Xuelei Peng ◽  
Chao Huang ◽  
Qi Qi ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Intramolecular Charge Transfer ◽  
Highly Efficient

o-Carborane-based triphenylamine dyads were explored, with highly efficient emissions in the solid state, induced by intramolecular charge transfer (ICT).

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