Molecular Orientation and Multilayer Formation of 1H,1H,8H,8H-Perfluorooctane-1,8-diol at the Air/Water Interface

2009 ◽  
Vol 113 (18) ◽  
pp. 6305-6310 ◽  
Author(s):  
Takanori Takiue ◽  
Fumiya Nakamura ◽  
Daiki Murakami ◽  
Tsubasa Fukuda ◽  
Aya Shuto ◽  
...  
2001 ◽  
Vol 74 (3) ◽  
pp. 421-425 ◽  
Author(s):  
Tomokiyo Doi ◽  
Takatoshi Kinoshita ◽  
Yoshiharu Tsujita ◽  
Hiroaki Yoshimizu

1968 ◽  
Vol 110 (4) ◽  
pp. 733-737 ◽  
Author(s):  
B. R. Malcolm

Molecular monolayers of poly-∈-benzyloxycarbonyl-l-lysine were studied at the air/water interface. Deuterium-exchange measurements and the surface area of the monolayer are consistent with a structure consisting of condensed ordered arrays of α-helices. Collapsed films removed from the surface and air-dried were examined by polarized infrared spectroscopy and electron diffraction and found to consist of molecules in the α-helical conformation. There is no indication of a conformational change during compression of the monolayer, and a series of transitions found in the force–area curve are interpreted as the consecutive formation of additional layers of molecules. Some of the factors that influence this almost perfect plastic behaviour are discussed.


2011 ◽  
Vol 115 (3) ◽  
pp. 471-477
Author(s):  
Takanori Takiue ◽  
Fumiya Nakamura ◽  
Hiroyasu Sakamoto ◽  
Hiroki Matsubara ◽  
Makoto Aratono

Hyomen Kagaku ◽  
1995 ◽  
Vol 16 (7) ◽  
pp. 463-467
Author(s):  
Susumu YAMADA ◽  
Yuhei SHIMOYAMA

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