Atomistic Simulation of the Surface Carbonation of Calcium and Magnesium Oxide Surfaces

2009 ◽  
Vol 113 (19) ◽  
pp. 8320-8328 ◽  
Author(s):  
Jeremy P. Allen ◽  
Stephen C. Parker ◽  
David W. Price
2008 ◽  
Vol 59 (6) ◽  
Author(s):  
Dan Macarovici ◽  
Viorel Paraschiv ◽  
Elisabeth-Jeanne Popovici

The behaviour of one sort of Romanian diatomite as precursor in the synthesis of calcium and magnesium silicates was studied. The calcination of this diatomite, 3 h at 10000C in air, does not produce major modifications in structure and composition. In the same conditions, the thermal reaction between diatomite and calcium carbonate leads to a mixture of calcium silicates (CaSiO3, Ca2SiO4, Ca3SiO5) whereas the reaction product with magnesium oxide is orthomagnesium silicate (Mg2SiO4 - forsterite). This sort of Romanian diatomite can play the same role as other silica sources in the synthesis of alkaline-earth silicates.


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