Kinetic Barriers of H-Atom Transfer Reactions in Alkyl, Allylic, and Oxoallylic Radicals as Calculated by Composite Ab Initio Methods

2009 ◽  
Vol 113 (11) ◽  
pp. 2473-2482 ◽  
Author(s):  
Carrigan J. Hayes ◽  
Donald R. Burgess
Keyword(s):  
Ab Initio ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Ab Initio Methods ◽  
Atom Transfer Reactions ◽  
Kinetic Barriers

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

Structure of the activated complex in atom-transfer reactions

1971 ◽  
Vol 93 (11) ◽  
pp. 2819-2820 ◽  
Author(s):  
Charles Sidney Johnson ◽  
Ann B. Gooch ◽  
Robert G. Griffin ◽  
Raymond Chang
Keyword(s):  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Activated Complex
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