Cooperative Energy Transfer Up-Conversion and Quantum Cutting Down-Conversion in Yb3+:TbF3 Nanocrystals Embedded Glass Ceramics

2009 ◽  
Vol 113 (16) ◽  
pp. 6406-6410 ◽  
Author(s):  
Daqin Chen ◽  
Yunlong Yu ◽  
Yuansheng Wang ◽  
Ping Huang ◽  
Fangyi Weng
2014 ◽  
Vol 936 ◽  
pp. 585-590 ◽  
Author(s):  
Liang Feng Niu ◽  
Wei Liang ◽  
Chang Zeng Wu ◽  
Yu Hua Wang

Tb3+, Er3+co-doped K2GdZr (PO4)3samples were prepared by solid-state reaction method and their photoluminescence (PL) properties were investigated in ultra-violet (UV) and vacuum ultra-violet (VUV) region. The results indicate that the energy transfers from Er3+to Gd3+and from Gd3+to Tb3+required for occurring of visible quantum cutting through down-conversion are efficient. In this cooperative energy transfer process, Gd3+is used as an intermediate of energy transfer between Er3+and Tb3+. The optimal quantum efficiency (QE) of this co-doped system K2GdZr (PO4)3: Er3+, Tb3+phosphor reached to 110%, suggesting a potential visible quantum cutting phosphor in practical application.


2013 ◽  
Vol 860-863 ◽  
pp. 124-127
Author(s):  
Mayuri Gandhi ◽  
Nayan Agrawal ◽  
Harshita Bhatia

In the present work, Cerium Fluoride (CeF3) was selected as the host material because of its High density, fast response and high radiation resistance, efficient absorption and energy transfer by host (to activator). Rare earths have been used to show the process of Quantum Cutting (QC) via energy transfer process between Tb3+ and Yb3+ incorporated in CeF3. For the synthesis of CeF3 nanoparticles codoped with Tb3+ and Yb3+ ion, co-precipitation route was employed. Different doping concentrations were prepared to study the changes that take place in the luminescence spectra of the composition. Thus, concentration dependent study of the fluorescence of CeF3: Tb3+, Yb3+ was carried out. These materials have great applications in solar cell devices as quantum efficiencies up to 200 % can be achieved.


2011 ◽  
Vol 11 (11) ◽  
pp. 9543-9549 ◽  
Author(s):  
Xueqin Cao ◽  
Li Li ◽  
Xiantao Wei ◽  
Yonghu Chen ◽  
Weiping Zhang ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (5) ◽  
pp. 4085-4089 ◽  
Author(s):  
Yuping Tai ◽  
Hanying Wang ◽  
Hui Wang ◽  
Jintao Bai

A two-step energy transfer was achieved in Er3+–Yb3+ co-doped transparent glass ceramics containing CaF2 nanocrystals, which involved down-conversion of an absorbed visible photon to two emitted near-infrared photons.


2012 ◽  
Vol 502 ◽  
pp. 136-139 ◽  
Author(s):  
Jia Yue Sun ◽  
Yi Ning Sun ◽  
Ji Cheng Zhu ◽  
Jun Hui Zeng ◽  
Hai Yan Du

An efficient near-infrared (NIR) quantum cutting (QC) Tb3+ and Yb3+ co-doped phosphor Sr3Gd(PO4)3 has been synthesized by conventional high temperature solid technique. Upon excitation of Tb3+ with a visible photon at 485 nm, two NIR photons could be emitted by Yb3+ through cooperative energy transfer (CTE) from Tb3+ to two Yb3+ ions. Excitation and emission spectra as well as fluorescence decay measurements have been carried out to examine the occurrence of cooperative energy transfer (CET ) from Tb3+ to Yb3+ ions. The result indicates Tb3+ and Yb3+ co-doped Sr3Gd(PO4)3 is potentially used as down-converter layer in silicon-based solar cell.


2017 ◽  
Vol 17 (6) ◽  
pp. 3163-3169 ◽  
Author(s):  
Shinan He ◽  
Haiping Xia ◽  
Qingyang Tang ◽  
Qiguo Sheng ◽  
Jianli Zhang ◽  
...  

2010 ◽  
Vol 19 (7) ◽  
pp. 077804 ◽  
Author(s):  
Wei Xian-Tao ◽  
Zhao Jiang-Bo ◽  
Chen Yong-Hu ◽  
Yin Min ◽  
Li Yong

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