A Crossed Molecular Beam Study of the Phenyl Radical Reaction with 1,3-Butadiene and its Deuterated Isotopologues

2009 ◽  
Vol 113 (6) ◽  
pp. 998-1006 ◽  
Author(s):  
Xibin Gu ◽  
Fangtong Zhang ◽  
Ralf I. Kaiser
Keyword(s):  
Molecular Beam ◽  
Radical Reaction ◽  
Phenyl Radical ◽  
Crossed Molecular Beam

Formation of the Phenyl Radical [C6H5(X2A1)] under Single Collision Conditions: A Crossed Molecular Beam and ab Initio Study

2010 ◽  
Vol 132 (8) ◽  
pp. 2672-2683 ◽  
Author(s):  
Fangtong Zhang ◽  
Brant Jones ◽  
Pavlo Maksyutenko ◽  
Ralf I. Kaiser ◽  
Christine Chin ◽  
...  
Keyword(s):  
Ab Initio ◽  
Molecular Beam ◽  
Phenyl Radical ◽  
Ab Initio Study ◽  
Single Collision ◽  
Crossed Molecular Beam

Crossed-beam studies of radical reaction dynamics:

1994 ◽  
Vol 72 (3) ◽  
pp. 660-672 ◽  
Author(s):  
R. Glen Macdonald ◽  
Kopin Liu Argonne ◽  
David M. Sonnenfroh ◽  
Di-Jia Liu
Keyword(s):  
Cross Sections ◽  
Molecular Beam ◽  
Radical Reaction ◽  
Reaction Cross ◽  
Translational Energy ◽  
Vibronic State ◽  
State Distribution ◽  
Title Reaction ◽  
Vibrational Ground State ◽  
Reaction Cross Sections

The title reaction has been studied in a crossed molecular beam apparatus. Both the product state distributions and the translational energy dependence of the reaction cross sections were measured under single collision conditions. Excellent agreement was found over a wide temperature range (26–3800 K) between rate constants deduced from the translational excitation function and recent thermal kinetic data. The rotational state distribution was found to be very cold compared to the reaction exothermicity, and could be described by a Boltzmann temperature of 110 K for all K-doublet levels. The vibronic state distribution was also found to be cold, with 70% of the products formed in the vibrational ground state. By comparing the molecular beam results for vibronic state distributions with those obtained from recent bulb experiments, it was conjectured that there appears to be a strong correlation between rotation in the reactants and bending excitation in the products.

Experimental and Computational Studies of the Phenyl Radical Reaction with Allene†

2007 ◽  
Vol 111 (29) ◽  
pp. 6881-6889 ◽  
Author(s):  
J. Park ◽  
I. V. Tokmakov ◽  
M. C. Lin
Keyword(s):  
Radical Reaction ◽  
Computational Studies ◽  
Phenyl Radical

scholarly journals Crossed molecular beam studies of the reactions of methyl radicals with iodoalkanes

1988 ◽  
Vol 89 (11) ◽  
pp. 6744-6752 ◽  
Author(s):  
Gary N. Robinson ◽  
Gilbert M. Nathanson ◽  
Robert E. Continetti ◽  
Yuan T. Lee
Keyword(s):  
Molecular Beam ◽  
Methyl Radicals ◽  
Crossed Molecular Beam
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