Free-Radical-Induced Oxidative and Reductive Degradation of Fibrate Pharmaceuticals: Kinetic Studies and Degradation Mechanisms

2009 ◽  
Vol 113 (7) ◽  
pp. 1287-1294 ◽  
Author(s):  
Behnaz Razavi ◽  
Weihua Song ◽  
William J. Cooper ◽  
John Greaves ◽  
Joonseon Jeong
Keyword(s):  
Free Radical ◽  
Kinetic Studies ◽  
Degradation Mechanisms ◽  
Reductive Degradation

Free-radical-induced oxidative and reductive degradation of N,N′-diethyl-m-toluamide (DEET): Kinetic studies and degradation pathway

2009 ◽  
Vol 43 (3) ◽  
pp. 635-642 ◽  
Author(s):  
Weihua Song ◽  
William J. Cooper ◽  
Barrie M. Peake ◽  
Stephen P. Mezyk ◽  
Michael G. Nickelsen ◽  
...  
Keyword(s):  
Free Radical ◽  
Kinetic Studies ◽  
Degradation Pathway ◽  
Reductive Degradation

Free-Radical-Induced Oxidative and Reductive Degradation of Fluoroquinolone Pharmaceuticals: Kinetic Studies and Degradation Mechanism

2009 ◽  
Vol 113 (27) ◽  
pp. 7846-7851 ◽  
Author(s):  
Hanoz Santoke ◽  
Weihua Song ◽  
William J. Cooper ◽  
John Greaves ◽  
George E. Miller
Keyword(s):  
Free Radical ◽  
Degradation Mechanism ◽  
Kinetic Studies ◽  
Reductive Degradation

Aqueous free-radical polymerization of PEGMEMA macromer: kinetic studies via an on-line 1H NMR technique

2012 ◽  
Vol 21 (10) ◽  
pp. 683-688 ◽  
Author(s):  
Vahid Najafi ◽  
Farshid Ziaee ◽  
Kourosh Kabiri ◽  
Mohammad Jalal Zohouriaan Mehr ◽  
Hossein Abdollahi ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
1H Nmr ◽  
Free Radical Polymerization ◽  
Kinetic Studies ◽  
On Line

THE MECHANISM OF ORGANOMERCURIAL OXIDATION BY MERCURIC SALTS

1960 ◽  
Vol 38 (1) ◽  
pp. 1-20 ◽  
Author(s):  
J. H. Robson ◽  
George F Wright
Keyword(s):  
Free Radical ◽  
Kinetic Studies ◽  
Mercuric Salt

It has been shown that the oxidation of organomercuric salts by inorganic mercuric salts is inhibited by oxygen, accelerated to some extent by acids, and will form esters as products even in the presence of much water. Moreover, the system will polymerize acrylonitrile. These evidences of free radical participation are substantiated by the formation of the same products when pernitrous acid replaces inorganic mercuric salt in the system. Kinetic studies show that radicals are involved in a self-regenerating chain in which active monomeric mercurous salt seems to be the carrier.

Free-radical homo- and copolymerization of vinyl acetate and n-butyl acrylate: Kinetic studies by online 1H NMR kinetic experiments

2011 ◽  
Vol 123 (1) ◽  
pp. 543-553 ◽  
Author(s):  
Mahdi Abdollahi ◽  
Bakhshali Massoumi ◽  
Mohammad Reza Yousefi ◽  
Farshid Ziaee
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
1H Nmr ◽  
Butyl Acrylate ◽  
Kinetic Studies
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