A Multinuclear Solid-State NMR Study of Alkali Metal Ions in Tetraphenylborate Salts, M[BPh4] (M = Na, K, Rb and Cs): What Is the NMR Signature of Cation−π Interactions?

2008 ◽  
Vol 112 (41) ◽  
pp. 10359-10364 ◽  
Author(s):  
Gang Wu ◽  
Victor Terskikh
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Metal Ions ◽  
Solid State Nmr ◽  
Alkali Metal Ions ◽  
Π Interactions ◽  
Nmr Study

scholarly journals Multinuclear NMR study of the interaction of the shift reagent lanthanide(III) bis(triphosphate) with alkali-metal ions in aqueous solution and in the solid state

1991 ◽  
Vol 30 (16) ◽  
pp. 3188-3191 ◽  
Author(s):  
Ravichandran. Ramasamy ◽  
Duarte. Mota de Freitas ◽  
Carlos F. G. C. Geraldes ◽  
Joop A. Peters
Keyword(s):  
Aqueous Solution ◽  
Solid State ◽  
Alkali Metal ◽  
Metal Ions ◽  
Shift Reagent ◽  
Alkali Metal Ions ◽  
Multinuclear Nmr ◽  
Nmr Study

scholarly journals Dynamic ionic radius of alkali metal ions in aqueous solution: a pulsed-field gradient NMR study

RSC Advances ◽  
2021 ◽  
Vol 11 (33) ◽  
pp. 20252-20257
Author(s):  
Kikuko Hayamizu ◽  
Yusuke Chiba ◽  
Tomoyuki Haishi
Keyword(s):  
Aqueous Solution ◽  
Alkali Metal ◽  
Metal Ions ◽  
Field Gradient ◽  
Ionic Radius ◽  
Alkali Metal Ions ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Nmr Study ◽  
Stokes Radius

Stokes radius (dynamic ionic radius) of the alkali metal ions versus the ionic radius (Rion) at 303 K. The dotted line is a guide for the 1 : 1 relation.

scholarly journals Solid NMR Study of the Ion-Exchange Properties on .GAMMA.-Titanium Phosphate with Alkali Metal Ions

2003 ◽  
Vol 14 (Supplement) ◽  
pp. 169-172 ◽  
Author(s):  
Noriko SUZUKI ◽  
Mami ITOH ◽  
Megumi IGARASHI ◽  
Yasushi KANZAKI ◽  
Yu KOMATSU
Keyword(s):  
Ion Exchange ◽  
Alkali Metal ◽  
Metal Ions ◽  
Titanium Phosphate ◽  
Alkali Metal Ions ◽  
Gamma Titanium ◽  
Nmr Study ◽  
Solid Nmr ◽  
Exchange Properties

scholarly journals Mobility of hydrated alkali metal ions in metallosupramolecular ionic crystals

2019 ◽  
Vol 10 (2) ◽  
pp. 587-593 ◽  
Author(s):  
Nobuto Yoshinari ◽  
Satoshi Yamashita ◽  
Yosuke Fukuda ◽  
Yasuhiro Nakazawa ◽  
Takumi Konno
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Alkali Metal Ions ◽  
Ionic Crystals ◽  
Ionic Solids ◽  
Ion Conducting

The ion-conducting behaviour of alkali metal ions in ionic solids (M6[1]·nH2O) resembles that in aqueous solutions; the solid-state conductivities increase in the order of M = Li+ < Na+ < K+.

A Joint Experimental and Theoretical Study of Cation−π Interactions:  Multiple-Decker Sandwich Complexes of Ferrocene with Alkali Metal Ions (Li+, Na+, K+, Rb+, Cs+)

2005 ◽  
Vol 127 (30) ◽  
pp. 10656-10666 ◽  
Author(s):  
Alireza Haghiri Ilkhechi ◽  
Jose M. Mercero ◽  
Iñaki Silanes ◽  
Michael Bolte ◽  
Matthias Scheibitz ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Ions ◽  
Theoretical Study ◽  
Alkali Metal Ions ◽  
Sandwich Complexes ◽  
Π Interactions
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