Atomistic Simulation of Micropore Structure, Surface Area, and Gas Sorption Properties for Amorphous Microporous Polymer Networks

2008 ◽  
Vol 112 (51) ◽  
pp. 20549-20559 ◽  
Author(s):  
Abbie Trewin ◽  
David J. Willock ◽  
Andrew I. Cooper
Keyword(s):  
Surface Area ◽  
Atomistic Simulation ◽  
Polymer Networks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Micropore Structure ◽  
Microporous Polymer ◽  
Structure Surface

scholarly journals Chemical modification of the polymer of intrinsic microporosity PIM-1 for enhanced hydrogen storage

Adsorption ◽  
2020 ◽  
Vol 26 (7) ◽  
pp. 1083-1091
Author(s):  
Mi Tian ◽  
Sébastien Rochat ◽  
Hamish Fawcett ◽  
Andrew D. Burrows ◽  
Christopher R. Bowen ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Surface Area ◽  
Hydrogen Adsorption ◽  
Sorption Properties ◽  
Bet Surface Area ◽  
Polymer Modification ◽  
Gas Sorption ◽  
Chemically Modified ◽  
Polymer Of Intrinsic Microporosity ◽  
Intrinsic Microporosity

Abstract A detailed investigation has been carried out of the pre-polymerisation modification of the polymer of intrinsic microporosity PIM-1 by the addition of two methyl (Me) groups to its spirobisindane unit to create a new chemically modified PIM-1 analogue, termed MePIM. Our work explores the effects of this modification on the porosity of PIM-1 and hence on its gas sorption properties. MePIM was successfully synthesised using either low (338 K) or high (423 K) temperature syntheses. It was observed that introduction of methyl groups to the spirobisindane part of PIM-1 generates additional microporous spaces, which significantly increases both surface area and hydrogen storage capacity. The BET surface area (N2 at 77 K) was increased by ~ 12.5%, resulting in a ~ 25% increase of hydrogen adsorption after modification. MePIM also maintains the advantages of good processability and thermal stability. This work provides new insights on a facile polymer modification that enables enhanced gas sorption properties.

Construction and carbon dioxide capture of microporous polymer networks with high surface area based on cross-linkable linear polyimides

2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Carbon Dioxide Capture ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Crosslinking Reaction ◽  
Adsorption Performance ◽  
Microporous Polymer

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.

scholarly journals Aromatic, microporous polymer networks with high surface area generated in Friedel–Crafts-type polycondensations

2011 ◽  
Vol 2 (10) ◽  
pp. 2186 ◽  
Author(s):  
Eduard Preis ◽  
Christian Widling ◽  
Ullrich Scherf ◽  
Satish Patil ◽  
Gunther Brunklaus ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
Polymer Networks ◽  
High Surface Area ◽  
Microporous Polymer

Enhanced gas-sorption properties of a high surface area, ultramicroporous magnesium formate

CrystEngComm ◽  
2015 ◽  
Vol 17 (3) ◽  
pp. 532-539 ◽  
Author(s):  
I. Spanopoulos ◽  
I. Bratsos ◽  
Ch. Tampaxis ◽  
A. Kourtellaris ◽  
A. Tasiopoulos ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Unit Cell ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Very High

The gas-sorption properties of a high surface area α-magnesium formate with an expanded unit cell are reported. The material is stable in NH3 and shows very high CH4/N2 (5.2) selectivity.

scholarly journals Developing Eco-Friendly and Cost-Effective Porous Adsorbent for Carbon Dioxide Capture

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1962
Author(s):  
Mahboubeh Nabavinia ◽  
Baishali Kanjilal ◽  
Noahiro Fujinuma ◽  
Amos Mugweru ◽  
Iman Noshadi
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Co2 Capture ◽  
High Surface ◽  
Scale Up ◽  
Polymer Networks ◽  
High Surface Area ◽  
Excellent Thermal Stability ◽  
Doped Polymers ◽  
Metal Doped

To address the issue of global warming and climate change issues, recent research efforts have highlighted opportunities for capturing and electrochemically converting carbon dioxide (CO2). Despite metal doped polymers receiving widespread attention in this respect, the structures hitherto reported lack in ease of synthesis with scale up feasibility. In this study, a series of mesoporous metal-doped polymers (MRFs) with tunable metal functionality and hierarchical porosity were successfully synthesized using a one-step copolymerization of resorcinol and formaldehyde with Polyethyleneimine (PEI) under solvothermal conditions. The effect of PEI and metal doping concentrations were observed on physical properties and adsorption results. The results confirmed the role of PEI on the mesoporosity of the polymer networks and high surface area in addition to enhanced CO2 capture capacity. The resulting Cobalt doped material shows excellent thermal stability and promising CO2 capture performance, with equilibrium adsorption of 2.3 mmol CO2/g at 0 °C and 1 bar for at a surface area 675.62 m2/g. This mesoporous polymer, with its ease of synthesis is a promising candidate for promising for CO2 capture and possible subsequent electrochemical conversion.

Ionic π-Conjugated Polymer Networks by Catalyst-Free Polymerization, Photoluminescence and Gas Sorption Behavior

2016 ◽  
Vol 217 (17) ◽  
pp. 1886-1898 ◽  
Author(s):  
Tomáš Faukner ◽  
Arnošt Zukal ◽  
Jiří Brus ◽  
Jiří Zedník ◽  
Jan Sedláček
Keyword(s):  
Conjugated Polymer ◽  
Polymer Networks ◽  
Sorption Behavior ◽  
Gas Sorption ◽  
Catalyst Free

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Gas-sorption properties of 6FDA-durene/1,4-phenylenediamine (pPDA) and 6FDA-durene/1,3-phenylenediamine (mPDA) copolyimides

2003 ◽  
Vol 90 (8) ◽  
pp. 2187-2193 ◽  
Author(s):  
Si-Xue Cheng ◽  
Tai-Shung Chung ◽  
Rong Wang ◽  
Rohit H. Vora
Keyword(s):  
Sorption Properties ◽  
Gas Sorption
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