Nanocasted Synthesis of Mesoporous LaCoO3 Perovskite with Extremely High Surface Area and Excellent Activity in Methane Combustion

2008 ◽  
Vol 112 (39) ◽  
pp. 15293-15298 ◽  
Author(s):  
Yangang Wang ◽  
Jiawen Ren ◽  
Yanqin Wang ◽  
Fengyuan Zhang ◽  
Xiaohui Liu ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Methane Combustion ◽  
Excellent Activity

PMMA-templating preparation and catalytic properties of high-surface-area three-dimensional macroporous La2CuO4 for methane combustion

2011 ◽  
Vol 175 (1) ◽  
pp. 209-215 ◽  
Author(s):  
Jing Yuan ◽  
Hongxing Dai ◽  
Lei Zhang ◽  
Jiguang Deng ◽  
Yuxi Liu ◽  
...  
Keyword(s):  
Surface Area ◽  
Catalytic Properties ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Methane Combustion

Synthesis of the high-surface-area CexBa1−xMnAl11Oycatalyst in reverse microemulsions using inexpensive inorganic salts as precursors

2005 ◽  
Vol 7 (7) ◽  
pp. 493-499 ◽  
Author(s):  
Fei Teng ◽  
Ping Xu ◽  
Zhijian Tian ◽  
Guoxing Xiong ◽  
Yunpeng Xu ◽  
...  
Keyword(s):  
High Activity ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Methane Combustion ◽  
Inorganic Salts ◽  
Reverse Microemulsions

The CexBa1−xMnAl11Ox catalysts are synthesized in reverse microemulsions using inexpensive inorganic salts as precursors, which have high surface area and high activity for methane combustion.

Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

2019 ◽  
Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Layer ◽  
Active Surface ◽  
Active Surface Area ◽  
High Concentration ◽  
Copper Electrodes ◽  
Surface Enhanced ◽  
Local Current

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>

scholarly journals Rugae-like FeP nanocrystal assembly on a carbon cloth: an exceptionally efficient and stable cathode for hydrogen evolution

Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  
Keyword(s):  
Gas Phase ◽  
Surface Area ◽  
Hydrogen Evolution ◽  
Hydrogen Generation ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Efficiency ◽  
Carbon Cloth ◽  
Nanocrystal Assembly

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.

High Surface Area NiCoP Nanostructure as Efficient Water Splitting Electrocatalyst for the Oxygen Evolution Reaction

2021 ◽  
pp. 111312
Author(s):  
Sisir Maity ◽  
Dheeraj Kumar Singh ◽  
Divya Bhutani ◽  
Suchitra Prasad ◽  
Umesh V. Waghmare ◽  
...  
Keyword(s):  
Surface Area ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Surface ◽  
High Surface Area
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