scholarly journals Intramolecular Charge-Transfer Dynamics in Covalently Linked Perylene−Dimethylaniline and Cyanoperylene−Dimethylaniline

2008 ◽  
Vol 112 (40) ◽  
pp. 9665-9674 ◽  
Author(s):  
Natalie Banerji ◽  
Gonzalo Angulo ◽  
Igor Barabanov ◽  
Eric Vauthey
Keyword(s):  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Charge Transfer Dynamics ◽  
Covalently Linked

Ultrafast excited state dynamics of fucoxanthin: excitation energy dependent intramolecular charge transfer dynamics

2011 ◽  
Vol 13 (22) ◽  
pp. 10762 ◽  
Author(s):  
Daisuke Kosumi ◽  
Toshiyuki Kusumoto ◽  
Ritsuko Fujii ◽  
Mitsuru Sugisaki ◽  
Yoshiro Iinuma ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Excitation Energy ◽  
Intramolecular Charge Transfer ◽  
Excited State Dynamics ◽  
Charge Transfer Dynamics ◽  
Energy Dependent

Fullerenes covalently linked to transition metals with organic ligands

2001 ◽  
Vol 73 (2) ◽  
pp. 275-278 ◽  
Author(s):  
Viatcheslav I. Sokolov ◽  
Marina N. Nefedova ◽  
Tatiana V. Potolokova ◽  
Vasily V. Bashilov
Keyword(s):  
Charge Transfer ◽  
Transition Metals ◽  
Nmr Spectra ◽  
Intramolecular Charge Transfer ◽  
Organic Ligands ◽  
Covalently Linked ◽  
C Nmr

Synthesis of molecules combining both fullerene and metallocene moieties separated by some spacer is discussed in connection with the possible intramolecular charge transfer. Two new kinds of spacers, =CH-CO- and -Pd-P-, have been introduced by using the corresponding reactions. Reaction of diazoacetyl ferrocene and cymantrene with C60 has been studied in detail and products characterized. 1,1'-Bis (diazoacetyl) ferrocene gave with C60 1:1 adduct to which the ansa-structure has been assigned on the basis of 1H and 13C NMR spectra. Palladium-h2-C60 complex with a bidentate ferrocenyl diphosphine as a ligand has been also prepared.

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