Miscibility and Hydrogen-Bonding Behavior in Organic/Inorganic Polymer Hybrids Containing Octaphenol Polyhedral Oligomeric Silsesquioxane

2008 ◽  
Vol 112 (35) ◽  
pp. 10821-10829 ◽  
Author(s):  
Ying-Chieh Yen ◽  
Shiao-Wei Kuo ◽  
Chih-Feng Huang ◽  
Jem-Kun Chen ◽  
Feng-Chih Chang
Keyword(s):  
Hydrogen Bonding ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Inorganic Polymer ◽  
Polymer Hybrids ◽  
Oligomeric Silsesquioxane

scholarly journals Progress in the Synthesis of Bifunctionalized Polyhedral Oligomeric Silsesquioxane

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2098 ◽  
Author(s):  
Mingyue Wang ◽  
Hong Chi ◽  
Joshy K.S. ◽  
Fuke Wang
Keyword(s):  
Optical Properties ◽  
Composite Materials ◽  
Aromatic Ring ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Industrial Research ◽  
Hybrid Nature ◽  
Backbone Chain ◽  
Polymer Hybrids ◽  
Recent Developments ◽  
Oligomeric Silsesquioxane

Polyhedral oligomeric silsesquioxane (POSS) has been considered as one of the most promising nanofillers in academic and industrial research due to its unique multifunctional nanostructure, easy functionalization, hybrid nature, and high processability. The progress of POSS has been extensive, particularly applications based on single- or multiple-armed POSS. In polymer hybrids, in order to enhance the properties, bifunctional POSS has been incorporated into the backbone chain of the polymer. This review summarizes recent developments in the synthesis, modification, and application of bifunctional POSS-containing composite materials. This includes amino-POSS, hydroxyl-POSS, aromatic ring-POSS, ether-POSS, and vinyl groups-POSS and their applications, exemplified by polyurethanes (PUs) and polyimides (PIs). In addition, the review highlights the enhancement of thermal, mechanical, and optical properties of the composites.

scholarly journals Star Poly(N-isopropylacrylamide) Tethered to Polyhedral Oligomeric Silsesquioxane (POSS) Nanoparticles by a Combination of ATRP and Click Chemistry

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Shiao-Wei Kuo ◽  
Jing-Long Hong ◽  
Yu-Chan Huang ◽  
Jem-Kun Chen ◽  
Shih-Kang Fan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Click Chemistry ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Star Polymers ◽  
Intramolecular Hydrogen Bonding ◽  
Solution Temperature ◽  
Critical Solution Temperature ◽  
Intramolecular Hydrogen ◽  
Oligomeric Silsesquioxane ◽  
Blue Photoluminescence

New star poly(N-isopropylacrylamide)-b-polyhedral oligomeric silsesquioxane (PNIPAm-b-POSS) copolymers were synthesized from octa-azido functionalized POSS (N3-POSS) and alkyne-PNIPAm, which was prepared using an alkyne-functionalized atom transfer radical polymerization (ATRP) initiator (propargyl 2-bromo-2-methylpropionamide), via click chemistry. These star PNIPAm-b-POSS copolymers undergo a sharp coil-globule transition in water at above 32°C changing from a hydrophilic state below this temperature to a hydrophobic state above it, which is similar to linear PNIPAm homopolymers. More interestingly, we found that these star polymers exhibited strong blue photoluminescence in water above a lower critical solution temperature (LCST). This photoluminescence was likely due to the constrained geometric freedom and relatively rigid structure caused by intramolecular hydrogen bonding within the star PNIPAm polymers, which exhibit an intrinsic fluorescent behavior.

Model Polyhedral Oligomeric Silsesquioxane Thin Films for Coating Applications

2002 ◽  
Author(s):  
Brent Viers ◽  
Shawn Phillips ◽  
Timothy Haddad ◽  
Alan Esker ◽  
Joe Polidan
Keyword(s):  
Thin Films ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Oligomeric Silsesquioxane
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