TPEPICO Spectroscopy of Vinyl Chloride and Vinyl Iodide: Neutral and Ionic Heats of Formation and Bond Energies

Nicholas S. Shuman; Melony A. Ochieng; Bálint Sztáray; Tomas Baer

doi:10.1021/jp8007255

TPEPICO Spectroscopy of Vinyl Chloride and Vinyl Iodide: Neutral and Ionic Heats of Formation and Bond Energies

The Journal of Physical Chemistry A ◽

10.1021/jp8007255 ◽

2008 ◽

Vol 112 (25) ◽

pp. 5647-5652 ◽

Cited By ~ 10

Author(s):

Nicholas S. Shuman ◽

Melony A. Ochieng ◽

Bálint Sztáray ◽

Tomas Baer

Keyword(s):

Vinyl Chloride ◽

Heats Of Formation ◽

Bond Energies ◽

Vinyl Iodide

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Heats of formation and crystal structures of some group 3 tetrahalides. N[MX4](c) (N = cesium or sodium, M = aluminum or gallium, and X = chlorine or bromine) and [(C6H5)4As][MCl4](c) (M = gallium or indium. Donor-acceptor bond energies for MX3-X- where M = Al, Ga, or In, and X = Cl or Br

Inorganic Chemistry ◽

10.1021/ic50152a022 ◽

1975 ◽

Vol 14 (10) ◽

pp. 2413-2416 ◽

Cited By ~ 18

Author(s):

Richard C. Gearhart ◽

James D. Beck ◽

Robert H. Wood

Keyword(s):

Crystal Structures ◽

Heats Of Formation ◽

Bond Energies ◽

Donor Acceptor ◽

Group 3

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898. Heats of formation and bond energies. Part IV. Hexacyclohexyloxycyclotriphosphazatriene, hexamethylcyclotriphosphazatriene, and octaphenylcyclotetraphosphazatetraene

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9600004649 ◽

1960 ◽

pp. 4649 ◽

Cited By ~ 3

Author(s):

A. F. Bedford ◽

C. T. Mortimer

Keyword(s):

Heats Of Formation ◽

Bond Energies

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HEATS OF FORMATION AND COÖRDINATE BOND ENERGIES OF SOME NICKEL(II) CHELATES

The Journal of Physical Chemistry ◽

10.1021/j100799a024 ◽

1963 ◽

Vol 67 (5) ◽

pp. 1049-1051 ◽

Cited By ~ 23

Author(s):

James L. Wood ◽

Mark M. Jones

Keyword(s):

Heats Of Formation ◽

Bond Energies ◽

Coordinate Bond

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583. Heats of formation and bond energies. Part I. Trisdiethylaminophosphine

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9590002913 ◽

1959 ◽

pp. 2913 ◽

Cited By ~ 9

Author(s):

P. A. Fowell ◽

C. T. Mortimer

Keyword(s):

Heats Of Formation ◽

Bond Energies

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368. Heats of formation and bond energies. Part IX. Trimethylaluminium and aluminium triacetate

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9630001978 ◽

1963 ◽

pp. 1978 ◽

Cited By ~ 15

Author(s):

C. T. Mortimer ◽

P. W. Sellers

Keyword(s):

Heats Of Formation ◽

Bond Energies

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PHOTOLYSE DE L'IODURE DE VINYLE EN SOLUTION DANS LE TETRACHLORURE DE CARBONE

Canadian Journal of Chemistry ◽

10.1139/v64-333 ◽

1964 ◽

Vol 42 (10) ◽

pp. 2262-2274 ◽

Cited By ~ 2

Author(s):

Pierre C. Roberge ◽

Jan A. Herman

Keyword(s):

Carbon Tetrachloride ◽

Vinyl Chloride ◽

Hydrogen Iodide ◽

Diffusion Controlled ◽

Vinyl Iodide

The photolysis of vinyl iodide in carbon tetrachloride solutions gives several products among which the most important are: acetylene, hydrogen iodide, iodine, ethylene, and vinyl chloride. A mechanism based on diffusion-controlled disproportionation of geminate radicals, as first proposed by Hamill, agrees well with the observed phenomena. To explain the diminishing production of ethylene and iodine with increasing concentration of the monomer, it is necessary to postulate a telomerization of the vinyl iodide.

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