Dipole Effects on Cation−π Interactions: Absolute Bond Dissociation Energies of Complexes of Alkali Metal Cations toN-methylaniline andN,N-dimethylaniline

Nuwan Hallowita; Damon R. Carl; P. B. Armentrout; M. T. Rodgers

doi:10.1021/jp800434v

Dipole Effects on Cation−π Interactions: Absolute Bond Dissociation Energies of Complexes of Alkali Metal Cations toN-methylaniline andN,N-dimethylaniline

The Journal of Physical Chemistry A ◽

10.1021/jp800434v ◽

2008 ◽

Vol 112 (35) ◽

pp. 7996-8008 ◽

Cited By ~ 26

Author(s):

Nuwan Hallowita ◽

Damon R. Carl ◽

P. B. Armentrout ◽

M. T. Rodgers

Keyword(s):

Alkali Metal ◽

Metal Cations ◽

Bond Dissociation Energies ◽

Alkali Metal Cations ◽

Π Interactions ◽

Bond Dissociation ◽

Dissociation Energies

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Inductive effects on cation–π interactions: Structures and bond dissociation energies of alkali metal cation–halobenzene complexes

International Journal of Mass Spectrometry ◽

10.1016/j.ijms.2009.01.006 ◽

2009 ◽

Vol 283 (1-3) ◽

pp. 35-47 ◽

Cited By ~ 20

Author(s):

Nuwan Hallowita ◽

Estima Udonkang ◽

Chunhai Ruan ◽

C.E. Frieler ◽

M.T. Rodgers

Keyword(s):

Alkali Metal ◽

Metal Cation ◽

Alkali Metal Cation ◽

Bond Dissociation Energies ◽

Π Interactions ◽

Bond Dissociation ◽

Dissociation Energies ◽

Inductive Effects

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Oxidation of transition-metal cations in the gas phase. Oxygen bond dissociation energies and formation of an excited-state product

The Journal of Physical Chemistry ◽

10.1021/j150608a004 ◽

1981 ◽

Vol 85 (8) ◽

pp. 942-944 ◽

Cited By ~ 80

Author(s):

Manfred M. Kappes ◽

Ralph H. Staley

Keyword(s):

Excited State ◽

Transition Metal ◽

Gas Phase ◽

Metal Cations ◽

Bond Dissociation Energies ◽

Transition Metal Cations ◽

Bond Dissociation ◽

Dissociation Energies ◽

Oxygen Bond

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ChemInform Abstract: DETERMINATION OF THE METAL-HYDROGEN AND METAL-METHYL BOND DISSOCIATION ENERGIES OF THE SECOND-ROW, GROUP 8 TRANSITION METAL CATIONS

Chemischer Informationsdienst ◽

10.1002/chin.198446095 ◽

1984 ◽

Vol 15 (46) ◽

Author(s):

M. L. MANDICH ◽

L. F. HALLE ◽

J. L. BEAUCHAMP

Keyword(s):

Transition Metal ◽

Metal Cations ◽

Bond Dissociation Energies ◽

Transition Metal Cations ◽

Bond Dissociation ◽

Dissociation Energies

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Determination of the metal-hydrogen and metal-methyl bond dissociation energies of the second-row, Group 8 transition metal cations

Journal of the American Chemical Society ◽

10.1021/ja00328a019 ◽

1984 ◽

Vol 106 (16) ◽

pp. 4403-4411 ◽

Cited By ~ 75

Author(s):

M. L. Mandich ◽

L. F. Halle ◽

J. L. Beauchamp

Keyword(s):

Transition Metal ◽

Metal Cations ◽

Bond Dissociation Energies ◽

Transition Metal Cations ◽

Bond Dissociation ◽

Dissociation Energies

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Cation-π interactions in gas-phase complexes formed by benzo-crown ethers and alkali metal cations

Rapid Communications in Mass Spectrometry ◽

10.1002/rcm.4898 ◽

2011 ◽

Vol 25 (5) ◽

pp. 672-674 ◽

Cited By ~ 11

Author(s):

Rafał Frański

Keyword(s):

Alkali Metal ◽

Gas Phase ◽

Crown Ethers ◽

Metal Cations ◽

Alkali Metal Cations ◽

Π Interactions

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Cation···π interactions: QTAIM and NBO studies on the interaction of alkali metal cations with heteroaromatic rings

Structural Chemistry ◽

10.1007/s11224-014-0433-3 ◽

2014 ◽

Vol 25 (5) ◽

pp. 1553-1561 ◽

Cited By ~ 3

Author(s):

Cuicui Liu ◽

Yanli Zeng ◽

Xiaoyan Li ◽

Shijun Zheng ◽

Xueying Zhang

Keyword(s):

Alkali Metal ◽

Metal Cations ◽

Alkali Metal Cations ◽

Π Interactions

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Bond dissociation energies of gaseous alkali metal hydroxides

Transactions of the Faraday Society ◽

10.1039/tf9696501537 ◽

1969 ◽

Vol 65 ◽

pp. 1537 ◽

Cited By ~ 33

Author(s):

D. H. Cotton ◽

D. R. Jenkins

Keyword(s):

Alkali Metal ◽

Bond Dissociation Energies ◽

Metal Hydroxides ◽

Bond Dissociation ◽

Dissociation Energies ◽

Alkali Metal Hydroxides

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“Cation-π Interactions” Detected by Mass Spectrometry; Selective Recognition of Alkali Metal Cations by aπ-Basic Molecular Cavity

Angewandte Chemie International Edition in English ◽

10.1002/anie.199513641 ◽

1995 ◽

Vol 34 (12) ◽

pp. 1364-1366 ◽

Cited By ~ 62

Author(s):

Fumiaki Inokuchi ◽

Yuji Miyahara ◽

Takahiko Inazu ◽

Seiji Shinkai

Keyword(s):

Mass Spectrometry ◽

Alkali Metal ◽

Metal Cations ◽

Selective Recognition ◽

Alkali Metal Cations ◽

Π Interactions

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ChemInform Abstract: OXIDATION OF TRANSITION-METAL CATIONS IN THE GAS PHASE. OXYGEN BOND DISSOCIATION ENERGIES AND FORMATION OF AN EXCITED-STATE PRODUCT

Chemischer Informationsdienst ◽

10.1002/chin.198128026 ◽

1981 ◽

Vol 12 (28) ◽

Author(s):

M. M. KAPPES ◽

R. H. STALEY

Keyword(s):

Excited State ◽

Transition Metal ◽

Gas Phase ◽

Metal Cations ◽

Bond Dissociation Energies ◽

Transition Metal Cations ◽

Bond Dissociation ◽

Dissociation Energies ◽

Oxygen Bond

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Cation-π Interactions Between Alkali Metal Cations and Neutral Double Bonds

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc20041050 ◽

2004 ◽

Vol 69 (5) ◽

pp. 1050-1062 ◽

Cited By ~ 5

Author(s):

Jiaxin Hu ◽

Leonard J. Barbour ◽

George W. Gokel

Keyword(s):

Alkali Metal ◽

Metal Cations ◽

Alkali Metal Cations ◽

Double Bonds ◽

Lariat Ethers ◽

X Ray ◽

Π Interactions ◽

X Ray Crystallography ◽

Sodium And Potassium

Two-armed lariat ethers having double bonds present in their side arms form stable complexes with sodium and potassium cations. When the double bonds are positioned appropriately, cation-π interactions are observed between the neutral double bonds and the macroring- bound cation as demonstrated by X-ray crystallography.

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