High-Temperature-Stable Au@SnO2Core/Shell Supported Catalyst for CO Oxidation

2008 ◽  
Vol 112 (7) ◽  
pp. 2244-2247 ◽  
Author(s):  
Kuai Yu ◽  
Zhengcui Wu ◽  
Qingrui Zhao ◽  
Benxia Li ◽  
Yi Xie
Keyword(s):  
High Temperature ◽  
Co Oxidation ◽  
Supported Catalyst

scholarly journals Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Xavier Isidro Pereira-Hernández ◽  
Andrew DeLaRiva ◽  
Valery Muravev ◽  
Deepak Kunwar ◽  
Haifeng Xiong ◽  
...  
Keyword(s):  
High Temperature ◽  
Co Oxidation ◽  
Vapor Phase ◽  
Ambient Pressure ◽  
Lattice Oxygen ◽  
Single Atom ◽  
Stable Form ◽  
Phase Synthesis ◽  
Vapor Phase Synthesis ◽  
High Temperature Vapor

Abstract In this work, we compare the CO oxidation performance of Pt single atom catalysts (SACs) prepared via two methods: (1) conventional wet chemical synthesis (strong electrostatic adsorption–SEA) with calcination at 350 °C in air; and (2) high temperature vapor phase synthesis (atom trapping–AT) with calcination in air at 800 °C leading to ionic Pt being trapped on the CeO2 in a thermally stable form. As-synthesized, both SACs are inactive for low temperature (<150 °C) CO oxidation. After treatment in CO at 275 °C, both catalysts show enhanced reactivity. Despite similar Pt metal particle size, the AT catalyst is significantly more active, with onset of CO oxidation near room temperature. A combination of near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and CO temperature-programmed reduction (CO-TPR) shows that the high reactivity at low temperatures can be related to the improved reducibility of lattice oxygen on the CeO2 support.

scholarly journals High-temperature heterogeneous catalysis in platinum nanoparticle – molten salt suspensions

2020 ◽  
Vol 10 (3) ◽  
pp. 625-629
Author(s):  
Behzad Tangeysh ◽  
Clarke Palmer ◽  
Horia Metiu ◽  
Michael J. Gordon ◽  
Eric W. McFarland
Keyword(s):  
Thermal Stability ◽  
Thermal Decomposition ◽  
High Temperature ◽  
Heterogeneous Catalysis ◽  
Co Oxidation ◽  
Molten Salt ◽  
Platinum Nanoparticles ◽  
Platinum Nanoparticle ◽  
Oxidation Activity

Suspensions of platinum nanoparticles (PtNPs) were formed in molten LiCl–LiBr–KBr via thermal decomposition of H2PtCl6, and subsequently evaluated for thermal stability and CO oxidation activity.

CeO2@SiO2 Core–Shell Nanostructure-Supported CuO as High-Temperature-Tolerant Catalysts for CO Oxidation

Langmuir ◽  
2019 ◽  
Vol 35 (26) ◽  
pp. 8658-8666 ◽  
Author(s):  
Yang-Yang Song ◽  
Lin-Ying Du ◽  
Wei-Wei Wang ◽  
Chun-Jiang Jia
Keyword(s):  
High Temperature ◽  
Co Oxidation ◽  
Core Shell

scholarly journals The influence of CePO4 nanorods on the CO oxidation activity of Au/GdPO4-rods

RSC Advances ◽  
2018 ◽  
Vol 8 (39) ◽  
pp. 21699-21711
Author(s):  
Yu Huanhuan ◽  
Chen Fayun ◽  
Zhubaolin Zhubaolin ◽  
Huang Weiping ◽  
Zhang Shoumin
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Co Oxidation ◽  
Oxidation Activity ◽  
Temperature Resistance ◽  
Ultrasound Method ◽  
High Temperature Resistance ◽  
Good Catalytic Activity ◽  
Content Of Gold ◽  
Good Support

A CePO4–GdPO4 composite was prepared by a general ultrasound method and could be a good support for gold nanocatalysts. Au/CePO4–GdPO4 catalysts with a low content of gold showed good catalytic activity, high temperature resistance and stability for CO oxidation.

An Experimental Research on Reactivity of Fe-Based Oxygen Carrier Using Coal Ash as Support

2012 ◽  
Vol 174-177 ◽  
pp. 534-538
Author(s):  
Si Mo Shi ◽  
Wu Qin ◽  
Chang Qing Dong ◽  
Wen Yan Li
Keyword(s):  
Grain Size ◽  
High Temperature ◽  
Co Oxidation ◽  
Experimental Research ◽  
Oxygen Carrier ◽  
Coal Ash ◽  
Experimental Results ◽  
Support Material ◽  
Oxygen Carriers

This paper is focused on the experimental research of Fe-based oxygen carriers using coal ash as support material. Influence of coal ash size, foamer content, temperature on reactivity of Fe-based oxygen carrier for CO oxidation were conducted in thermogravimetry analyzer (TGA). Experimental results show that conversion of the oxygen carrier could attain 100% under 750 °C, and samples that made from mean coal ash grain size of 0.06 mm are more active than that of 0.09 mm, which prove tiny coal ash grain size can enhance reactivity of oxygen carriers. Besides, reactivity of oxygen carriers under 850 °C are lower than 750 °C for that relative high temperature would cause sintering of the Fe-based oxygen carriers.

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