Characterizing Solvent Dynamics in Nanoscopic Silica Sol–Gel Glass Pores by 2D-IR Spectroscopy of an Intrinsic Vibrational Probe

2014 ◽  
Vol 118 (44) ◽  
pp. 25567-25578 ◽  
Author(s):  
Christopher J. Huber ◽  
Aaron M. Massari
RSC Advances ◽  
2021 ◽  
Vol 11 (13) ◽  
pp. 7732-7737
Author(s):  
Fenying Wang ◽  
Dan Wang ◽  
Tingting Wang ◽  
Yu Jin ◽  
Baoping Ling ◽  
...  

Fluorescent molecularly imprinted polymer (FMIP) gains great attention in many fields due to their low cost, good biocompatibility and low toxicity. Here, a high-performance FMIP was prepared based on the autocatalytic silica sol–gel reaction.


Author(s):  
Jeannette Ruf ◽  
Peter Hamm ◽  
David Buhrke

Two vibrational modes in a cyanobacterial protein were isolated with isotope labeling and studied with 2D-IR spectroscopy.


2021 ◽  
Vol 155 (4) ◽  
pp. 040903
Author(s):  
Megan C. Thielges
Keyword(s):  

2021 ◽  
Vol 12 (7) ◽  
pp. 1786-1792
Author(s):  
Erin R. Birdsall ◽  
Megan K. Petti ◽  
Vivek Saraswat ◽  
Joshua S. Ostrander ◽  
Michael S. Arnold ◽  
...  

2005 ◽  
Vol 885 ◽  
Author(s):  
Krithi Shetty ◽  
Shihuai Zhao ◽  
Wei Cao ◽  
Naidu V. Seetala ◽  
Debasish Kuila

ABSTRACTThe goal of this research is to investigate the activities of a non-noble nano-catalyst (Ni/SiO2) using Si-microreactors for steam reforming of methanol to produce hydrogen for fuel cells. The supported catalyst was synthesized by sol-gel method using Ni (II) salts and Si(C2H5O)4 as starting materials. EDX results indicate that the actual loading of Ni (5-6%) is lower than the intended loading of 12 %. The specific surface area of the silica sol-gel encapsulated Ni nano-catalyst is 452 m2/g with an average pore size of ∼ 3 nm. Steam reforming reactions have been carried out in a microreactor with 50 µm channels in the temperature range of 180-240 °C and atmospheric pressure. Results show 53% conversion of methanol with a selectivity of 74 % to hydrogen at 5 l/min and 200 °C. The magnetic properties of the catalysts were performed using a Vibrating Sample Magnetometer (VSM) to study the activity of the catalysts before and after the steam reforming reactions. The VSM results indicate much higher activity in the microreactor compared to macro-reactor and Ni forms non-ferromagnetic species faster in the microreactor.


1987 ◽  
Vol 153 (Part_1_2) ◽  
pp. 27-36 ◽  
Author(s):  
H. Rosenberger ◽  
H. Bürger ◽  
H. Schütz ◽  
G. Scheler ◽  
G. Maenz

Author(s):  
Yew Keong Choong ◽  
Su-Qin Sun ◽  
Qun Zhou ◽  
Zakiah Ismail ◽  
Badrul Amini Abdul Rashid ◽  
...  

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