Understanding the Biosynthesis and Catalytic Activity of Pd, Pt, and Ag Nanoparticles in Hydrogenation and Suzuki Coupling Reactions at the Nano–Bio Interface

2014 ◽  
Vol 118 (42) ◽  
pp. 24623-24632 ◽  
Author(s):  
Sujoy K. Das ◽  
Thanusu Parandhaman ◽  
Nagaraju Pentela ◽  
A. K. M. Maidul Islam ◽  
Asit Baran Mandal ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ag Nanoparticles ◽  
Suzuki Coupling ◽  
Coupling Reactions

A graphdiyne-based carbon material for electroless deposition and stabilization of sub-nanometric Pd catalysts with extremely high catalytic activity

2019 ◽  
Vol 7 (21) ◽  
pp. 13142-13148 ◽  
Author(s):  
Liang-Liang Yang ◽  
Hong-Juan Wang ◽  
Juan Wang ◽  
Yu Li ◽  
Wen Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Material ◽  
Electroless Deposition ◽  
Suzuki Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Pd Catalysts ◽  
Catalytic Activities

A new graphdiyne-based carbon material was synthesized as an ideal substrate for electroless deposition and stabilization of sub-nanometric Pd catalysts, which showed extremely high catalytic activities for the reduction of nitroarenes and Suzuki coupling reactions.

Construction of light-harvesting system for enhanced catalytic performance of Pd nanoframes toward Suzuki coupling reaction

2017 ◽  
Vol 5 (21) ◽  
pp. 10150-10153 ◽  
Author(s):  
Lini Yang ◽  
Qi Zhan ◽  
Zhenni Wang ◽  
Qiang Chen ◽  
Jing Tong ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Light Harvesting ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Catalytic Performance ◽  
Coupling Reactions ◽  
Suzuki Coupling Reaction

Au octahedra have been encapsulated into Pd nanoframes to further enhance the catalytic activity of Pd nanoframes toward Suzuki coupling reactions.

A Pd/CNT-SiC monolith as a robust catalyst for Suzuki coupling reactions

2014 ◽  
Vol 16 (23) ◽  
pp. 11178-11181 ◽  
Author(s):  
Hua Yuan ◽  
Hongyang Liu ◽  
Bingsen Zhang ◽  
Liyun Zhang ◽  
Haihua Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Suzuki Coupling ◽  
Coupling Reactions ◽  
Step Method

A Pd/CNT-SiC monolith prepared by a simple two-step method exhibits robust catalytic activity and recycling ability in Suzuki coupling reactions.

Malus domestica Mediated Synthesis of Palladium Nanoparticles and Investigation of Their Catalytic Activity Towards the Suzuki Coupling Reactions

2018 ◽  
Vol 10 (3) ◽  
pp. 373-377 ◽  
Author(s):  
Farah Qazi ◽  
Zakir Hussain ◽  
Soneela Asghar ◽  
Ghayoor Abbas ◽  
Muhammad Riaz
Keyword(s):  
Gas Chromatography ◽  
Catalytic Activity ◽  
Malus Domestica ◽  
Palladium Nanoparticles ◽  
Suzuki Coupling ◽  
Coupling Reactions ◽  
X Rays ◽  
Fruit Extract ◽  
Vis Spectroscopy ◽  
Ft Ir

Synthesis of nanoparticles through green methods is considered to be more eco-friendly and facile as compared to conventional physical and chemical methods. In this work, an environmental friendly method to synthesize palladium nanoparticles (Pd-NPs) by using a fruit extract has been reported. This extract obtained from Malus domestica (apple); acted as a source of reducing agent and functioned as a capping agent as well. The Pd-NPs were monitored and characterized by ultraviolet-visible (UV-Vis) spectroscopy; powder X-rays diffraction (XRD), scanning electron microscopy (SEM) and Fourier-transform infra-red (FT-IR) spectroscopy. FT-IR spectra revealed the presence of abundant amounts of ascorbic acid in the fruit extract which is assumed to reduce the Palladium chloride to Pd-NPs. XRD results confirmed the crystalline nature of Pd-NPs (JCPDS: No. 05-0681, space group: Fm3m (225)). These nanoparticles were further investigated for their catalytic activity towards the Suzuki coupling reactions where by employing only 2 mol% of the catalyst loading these Pd-NPs demonstrated excellent catalytic activity. Progress and completion of reactions were monitored by gas chromatography (GC) while products formed were characterized by gas chromatography-mass spectrometry (GC-MS), FT-IR as well as from their melting points data. Pd-NPs showed excellent catalytic activity; thereby suggesting their potential and scope for various other catalytic transformations.

Anchoring Positively Charged Pd Single Atoms in Ordered Porous Ceria to Boost Catalytic Activity and Stability in Suzuki Coupling Reactions

Small ◽  
2020 ◽  
Vol 16 (43) ◽  
pp. 2001782
Author(s):  
Xueqin Tao ◽  
Ran Long ◽  
Di Wu ◽  
Yangguang Hu ◽  
Ganhua Qiu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Suzuki Coupling ◽  
Coupling Reactions ◽  
Single Atoms ◽  
Ordered Porous ◽  
Positively Charged

Palladium(II) complexes comprising naphthylamine and biphenylamine based Schiff base ligands: Synthesis, structure and catalytic activity in Suzuki coupling reactions

2020 ◽  
Vol 914 ◽  
pp. 121220
Author(s):  
Veerasamy Nagalakshmi ◽  
Munusamy Sathya ◽  
Muniyappan Premkumar ◽  
Dhananjayan Kaleeswaran ◽  
Galmari Venkatachalam ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Suzuki Coupling ◽  
Coupling Reactions ◽  
Schiff Base Ligands

Synthesis of palladium-bidentate complex and its application in Sonogashira and Suzuki coupling reactions

2014 ◽  
Vol 68 (5) ◽  
Author(s):  
Boumediene Haddad ◽  
Didier Villemin ◽  
El-habib Belarbi
Keyword(s):  
Catalytic Activity ◽  
Bond Formation ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Complex Iii ◽  
Sonogashira Reaction ◽  
Coupling Reactions ◽  
Imidazolium Salt ◽  
Bidentate Complex ◽  
Phenylboronic Acids

AbstractA new palladium-bidentate complex [m-C6H4(CH2ImMe)2(PdCl2)] (III) was prepared in two steps. In the first step, [m-C6H4(CH2ImMeAgCl)2] (II) (Im = imidazole moiety) was obtained by reacting imidazolium salt [m-C6H4(CH2ImMe)2]Cl2 (I) (prepared by quaternisation of Nmethylimidazole with 1,3-bis(chloromethyl)benzene) and Ag2O in CH2Cl2. In the next step, treatment of (II) with Pd(CH3CN)2Cl2 afforded complex III which was evaluated for its catalytic activity for C-C bond-formation reactions by examining the coupling reaction of 3-iodoanisole with phenylacetylene in the Sonogashira reaction. In addition, 3-methoxybiphenyls were obtained with good to excellent yields by Suzuki coupling reactions of 3-iodoanisole with phenylboronic acids or phenylborates salts in the presence of this complex.

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