Substrate, Molecular Structure, and Solvent Effects in 2D Self-Assembly via Hydrogen and Halogen Bonding

2014 ◽  
Vol 118 (44) ◽  
pp. 25505-25516 ◽  
Author(s):  
Riccardo Gatti ◽  
Jennifer M. MacLeod ◽  
Josh A. Lipton-Duffin ◽  
Andrey G. Moiseev ◽  
Dmitrii F. Perepichka ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solvent Effects ◽  
Self Assembly ◽  
Halogen Bonding

scholarly journals Halogen Bonding in Bicomponent Monolayers: Self-Assembly of a Homologous Series of Iodinated Perfluoroalkanes with Bipyridine

Langmuir ◽  
2021 ◽  
Author(s):  
Jonathan A. Davidson ◽  
Marco Sacchi ◽  
Fabrice Gorrec ◽  
Stuart M. Clarke ◽  
Stephen J. Jenkins
Keyword(s):  
Self Assembly ◽  
Homologous Series ◽  
Halogen Bonding

Effects of the position and number of bromine substituents on the concentration-mediated 2D self-assembly of phenanthrene derivatives

2016 ◽  
Vol 18 (10) ◽  
pp. 7208-7215 ◽  
Author(s):  
Xingyu Hu ◽  
Bao Zha ◽  
Yican Wu ◽  
Xinrui Miao ◽  
Wenli Deng
Keyword(s):  
Self Assembly ◽  
Driving Force ◽  
Halogen Bonding ◽  
The Self

Br⋯Br halogen bonding exists in the self-assembly of 2,7-DBHP, whereas the driving force for the assembly of 3,6-DBHP is Br⋯Br vdWs type interactions.

Controllable Orientation of Ester-Group-Induced Intermolecular Halogen Bonding in a 2D Self-Assembly

2016 ◽  
Vol 7 (16) ◽  
pp. 3164-3170 ◽  
Author(s):  
Bao Zha ◽  
Meiqiu Dong ◽  
Xinrui Miao ◽  
Kai Miao ◽  
Yi Hu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Halogen Bonding ◽  
Ester Group

Effect of the Molecular Structure on the Hierarchical Self-Assembly of Semifluorinated Alkanes at the Air/Water Interface

Langmuir ◽  
2011 ◽  
Vol 27 (14) ◽  
pp. 8776-8786 ◽  
Author(s):  
Laurence de Viguerie ◽  
Rabea Keller ◽  
Ulrich Jonas ◽  
Rüdiger Berger ◽  
Christopher G. Clark ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Self Assembly ◽  
Water Interface ◽  
Semifluorinated Alkanes ◽  
Air Water Interface

Cyclic networks of halogen-bonding interactions in molecular self-assemblies: a theoretical N—X...NversusC—X...N investigation

2017 ◽  
Vol 73 (2) ◽  
pp. 179-187
Author(s):  
Ruben D. Parra ◽  
Álvaro Castillo
Keyword(s):  
Electron Density ◽  
Self Assembly ◽  
Metal Ion ◽  
Halogen Atom ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Nbo Analysis ◽  
Binding Energies ◽  
Cyclic Network ◽  
Ability To Drive

The geometries and energetics of molecular self-assembly structures that contain a sequential network of cyclic halogen-bonding interactions are investigated theoretically. The strength of the halogen-bonding interactions is assessed by examining binding energies, electron charge transfer (NBO analysis) and electron density at halogen-bond critical points (AIM theory). Specifically, structural motifs having intramolecular N—X...N (X= Cl, Br, or I) interactions and the ability to drive molecular self-assemblyviathe same type of interactions are used to construct larger self-assemblies of up to three unit motifs. N—X...N halogen-bond cooperativity as a function of the self-assembly size, and the nature of the halogen atom is also examined. The cyclic network of the halogen-bonding interactions provides a suitable cavity rich in electron density (from the halogen atom lone pairs not involved in the halogen bonds) that can potentially bind an electron-deficient species such as a metal ion. This possibility is explored by examining the ability of the N—X...N network to bind Na+. Likewise, molecular self-assembly structures driven by the weaker C—X...N halogen-bonding interactions are investigated and the results compared with those of their N—X...N counterparts.

scholarly journals One “Click” access to self-complementary molecular modules for halogen bonding

RSC Advances ◽  
2016 ◽  
Vol 6 (43) ◽  
pp. 36723-36727 ◽  
Author(s):  
G. Cavallo ◽  
P. Metrangolo ◽  
T. Pilati ◽  
G. Resnati ◽  
A. Scrivanti ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Self Assembly ◽  
Halogen Bonding

The application of “click chemistry” has proved its efficacy for the construction of novel molecular modules for halogen bonding driven self-assembly.

Halogen Bonding Driven Self-Assembly of Fluorocarbons and Hydrocarbons

ChemInform ◽  
2004 ◽  
Vol 35 (4) ◽  
Author(s):  
Pierangelo Metrangolo ◽  
Tullio Pilati ◽  
Giuseppe Resnati ◽  
Andrea Stevenazzi
Keyword(s):  
Self Assembly ◽  
Halogen Bonding
Sign in / Sign up

Export Citation Format

Share Document