scholarly journals Electrolytic Conditioning of a Magnesium Aluminum Chloride Complex for Reversible Magnesium Deposition

2014 ◽  
Vol 118 (48) ◽  
pp. 27623-27630 ◽  
Author(s):  
Christopher J. Barile ◽  
Elizabeth C. Barile ◽  
Kevin R. Zavadil ◽  
Ralph G. Nuzzo ◽  
Andrew A. Gewirth
Keyword(s):  
Aluminum Chloride ◽  
Chloride Complex

Reaction of the Tetramethylcyclobutadiene-Aluminum Chloride Complex with Dienophilic Esters

Synthesis ◽  
1971 ◽  
Vol 1971 (03) ◽  
pp. 139-140 ◽  
Author(s):  
J. B. KOSTER ◽  
G. J. TIMMERMANS ◽  
H. VAN BEKKUM
Keyword(s):  
Aluminum Chloride ◽  
Chloride Complex

Fragmentation-acetylation of isooctane with acetyl chloride-aluminum chloride complex

1969 ◽  
Vol 10 (30) ◽  
pp. 2581-2584 ◽  
Author(s):  
I. Tabushi ◽  
K. Fujita ◽  
R. Oda ◽  
M. Tsuboi
Keyword(s):  
Aluminum Chloride ◽  
Acetyl Chloride ◽  
Chloride Complex

Acylation of aromatic substrates with ketenes. An example of vinyl oxocation reactivity

1980 ◽  
Vol 58 (12) ◽  
pp. 1198-1205 ◽  
Author(s):  
K. R. Fountain ◽  
Pamela Heinze ◽  
Mark Sherwood ◽  
Dave Maddex ◽  
Greg Gerhardt
Keyword(s):  
Isotope Effect ◽  
Aluminum Chloride ◽  
Kinetic Isotope Effect ◽  
Chloride Complex ◽  
Chloride Complexes ◽  
Aromatic Substrates ◽  
Kinetic Isotope ◽  
Resonance Stabilization

Acylations of aromatic substrates with ketenes involve the reactivity of species similar to vinyl cations. Resonance stabilization of ketene – aluminum chloride complexes seems to make these complexes less reactive than corresponding vinyl cations.The kinetic isotope effect of the reaction with dimethylketene and benzene is 1.06, compatible with vinylcation cases, but not with acylation with CH3COBF4 types of electrophiles.Substrate specificity was determined from k (toluene)/k (benzene) values. It was 47.2 for dimethylketene and 173.7 for diphenylketene. The diphenylketene – aluminum chloride complex could be isolated.

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