Physicochemical Properties of Three Ionic Liquids Containing a Tetracyanoborate Anion and Their Lithium Salt Mixtures

2014 ◽  
Vol 118 (29) ◽  
pp. 8772-8781 ◽  
Author(s):  
Nédher Sanchez-Ramirez ◽  
Vitor L. Martins ◽  
Rômulo A. Ando ◽  
Fernanda F. Camilo ◽  
Sérgio M. Urahata ◽  
...  
2004 ◽  
Vol 57 (2) ◽  
pp. 139 ◽  
Author(s):  
Masahiro Yoshizawa ◽  
Asako Narita ◽  
Hiroyuki Ohno

Zwitterionic liquids composed of a tethered cation and anion were synthesized and their thermal properties and ionic conductivity were investigated as novel ionic liquids especially for electrochemical applications. We prepared nine zwitterions in this study. In addition, this paper includes 36 kinds of zwitterions already reported in order to discuss the relationship between the zwitterion structure and their properties. Most zwitterions melt above 100°C; their melting points are generally higher than that of simple ionic liquids. When an equimolar amount of lithium salt (LiTFSI, LiBETI, LiCF3SO3, LiBF4, or LiClO4) was added to the zwitterion, the mixture showed only a glass transition temperature Tg. The Tg values of the zwitterionic liquid/salt mixture showed the lowest value of –37°C when mixed with LiTFSI. This mixture also showed the highest ionic conductivity of 8.9 × 10–4 S cm–1 at 100°C. There is a good relationship between Tg and the ionic conductivity of the zwitterionic liquid/lithium salt mixtures.


2021 ◽  
pp. 116452
Author(s):  
Tomasz Rzemieniecki ◽  
Marta Wojcieszak ◽  
Katarzyna Materna ◽  
Tadeusz Praczyk ◽  
Juliusz Pernak

2010 ◽  
Vol 22 (3) ◽  
pp. 1203-1208 ◽  
Author(s):  
Qian Zhou ◽  
Kendall Fitzgerald ◽  
Paul D. Boyle ◽  
Wesley A. Henderson

2009 ◽  
Vol 38 (7) ◽  
pp. 714-715 ◽  
Author(s):  
Takatsugu Kanatani ◽  
Kazuhiko Matsumoto ◽  
Rika Hagiwara

2016 ◽  
Vol 415 ◽  
pp. 1-7 ◽  
Author(s):  
Gyanendra Sharma ◽  
Ramesh L. Gardas ◽  
Alberto Coronas ◽  
G. Venkatarathnam

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