Reactions of Atomic Hydrogen with Formic Acid and Carbon Monoxide in Solid Parahydrogen II: Deuterated Reaction Studies

2014 ◽  
Vol 118 (36) ◽  
pp. 7653-7662 ◽  
Author(s):  
William R. Wonderly ◽  
David T. Anderson
Keyword(s):  
Carbon Monoxide ◽  
Formic Acid ◽  
Atomic Hydrogen

Reactions of Atomic Hydrogen with Formic Acid and Carbon Monoxide in Solid Parahydrogen I: Anomalous Effect of Temperature

2014 ◽  
Vol 118 (36) ◽  
pp. 7640-7652 ◽  
Author(s):  
Leif O. Paulson ◽  
Fredrick M. Mutunga ◽  
Shelby E. Follett ◽  
David T. Anderson
Keyword(s):  
Carbon Monoxide ◽  
Formic Acid ◽  
Atomic Hydrogen ◽  
Effect Of Temperature ◽  
Anomalous Effect

Oxidation of carbon monoxide and formic acid on bulk and nanosized Pt–Co alloys

2011 ◽  
Vol 16 (2) ◽  
pp. 587-595 ◽  
Author(s):  
Maja D. Obradović ◽  
Amalija V. Tripković ◽  
Snežana Lj. Gojković
Keyword(s):  
Carbon Monoxide ◽  
Formic Acid ◽  
Co Alloys ◽  
Oxidation Of Carbon Monoxide

scholarly journals Tropospheric Emission Spectrometer (TES) satellite observations of ammonia, methanol, formic acid, and carbon monoxide over the Canadian oil sands: validation and model evaluation

2015 ◽  
Vol 8 (12) ◽  
pp. 5189-5211 ◽  
Author(s):  
M. W. Shephard ◽  
C. A. McLinden ◽  
K. E. Cady-Pereira ◽  
M. Luo ◽  
S. G. Moussa ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Air Quality ◽  
Formic Acid ◽  
Model Evaluation ◽  
Oil Sands ◽  
Field Campaign ◽  
Infrared Observations ◽  
Multi Scale ◽  
Global Environmental ◽  
Scale Modelling

Abstract. The wealth of air quality information provided by satellite infrared observations of ammonia (NH3), carbon monoxide (CO), formic acid (HCOOH), and methanol (CH3OH) is currently being explored and used for a number of applications, especially at regional or global scales. These applications include air quality monitoring, trend analysis, emissions, and model evaluation. This study provides one of the first direct validations of Tropospheric Emission Spectrometer (TES) satellite-retrieved profiles of NH3, CH3OH, and HCOOH through comparisons with coincident aircraft profiles. The comparisons are performed over the Canadian oil sands region during the intensive field campaign (August–September, 2013) in support of the Joint Canada–Alberta Implementation Plan for Oil Sands Monitoring (JOSM). The satellite/aircraft comparisons over this region during this period produced errors of (i) +0.08 ± 0.25 ppbv for NH3, (ii) +7.5 ± 23 ppbv for CO, (iii) +0.19 ± 0.46 ppbv for HCOOH, and (iv) −1.1 ± 0.39 ppbv for CH3OH. These values mostly agree with previously estimated retrieval errors; however, the relatively large negative bias in CH3OH and the significantly greater positive bias for larger HCOOH and CO values observed during this study warrant further investigation. Satellite and aircraft ammonia observations during the field campaign are also used in an initial effort to perform preliminary evaluations of Environment Canada's Global Environmental Multi-scale – Modelling Air quality and CHemistry (GEM-MACH) air quality modelling system at high resolution (2.5 × 2.5 km2). These initial results indicate a model underprediction of ~ 0.6 ppbv (~ 60 %) for NH3, during the field campaign period. The TES/model CO comparison differences are ~ +20 ppbv (~ +20 %), but given that under these conditions the TES/aircraft comparisons also show a small positive TES CO bias indicates that the overall model underprediction of CO is closer to ~ 10 % at 681 hPa (~ 3 km) during this period.

scholarly journals Mariner 6: Ultraviolet spectrum of Mars upper atmosphere

1971 ◽  
Vol 40 ◽  
pp. 253-256 ◽  
Author(s):  
C. A. Barth ◽  
W. G. Fastie ◽  
C. W. Hord ◽  
J. B. Pearce ◽  
K. K. Kelly ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Spectral Region ◽  
Atomic Hydrogen ◽  
Atomic Oxygen ◽  
Ultraviolet Spectrum ◽  
Upper Atmosphere

Emission features from ionized carbon dioxide and carbon monoxide were measured in the 1900- to 4300-Å spectral region. The Lyman-α 1216-Å line of atomic hydrogen and the 1304-, 1356-, and 2972-Å lines of atomic oxygen were observed.

ACTION OF HIGH SPEED ELECTRONS ON METHANE, OXYGEN AND CARBON MONOXIDE

1930 ◽  
Vol 3 (3) ◽  
pp. 241-251 ◽  
Author(s):  
J. C. McLennan F.R.S. ◽  
J. V. S. Glass B.A.
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Water Vapor ◽  
Formic Acid ◽  
Total Pressure ◽  
High Speed ◽  
Reaction Rate ◽  
First Order ◽  
Gaseous Products ◽  
Retarding Effect

This paper deals with the action of cathode rays on gases and gas mixtures. Methane, methane-oxygen mixtures, carbon monoxide and carbon monoxide-oxygen mixtures were examined. Methane gave small percentages of hydrogen and ethane. Methane and oxygen mixtures gave as gaseous products, carbon monoxide, carbon dioxide and hydrogen, the only other products being water and formic acid. The relative proportions of the products do not vary widely under a wide variation of conditions.The reaction was found to be of the first order with respect to pressure. The reaction rate increases linearly with the voltage up to a certain value, after which it becomes nearly independent of the voltage.The action of cathode rays on carbon monoxide produces carbon dioxide and a solid brown suboxide which is extremely soluble in water, and its composition corresponds to a formula (C3O)n. If the carbon monoxide is moist, no visible amount of solid or liquid is found and there is less carbon dioxide.Carbon monoxide-oxygen mixtures under the action of cathode rays form carbon dioxide. Presence of water vapor has a retarding effect on the reaction. For mixtures of the same composition the reaction rate is proportional to the total pressure. For dry mixtures the product increases with the carbon monoxide present; when moist it is much less, and independent of the carbon monoxide.

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