Atmospheric Reaction of Cl + Methacrolein: A Theoretical Study on the Mechanism, and Pressure- and Temperature-Dependent Rate Constants

2014 ◽  
Vol 118 (20) ◽  
pp. 3541-3551 ◽  
Author(s):  
Cuihong Sun ◽  
Baoen Xu ◽  
Shaowen Zhang
Keyword(s):  
Rate Constants ◽  
Theoretical Study ◽  
Temperature Dependent ◽  
Dependent Rate ◽  
Atmospheric Reaction

scholarly journals The Kinetics of the Reaction C2H5• + HI → C2H6 + I• over an Extended Temperature Range (213–623 K): Experiment and Modeling

2015 ◽  
Vol 229 (10-12) ◽  
Author(s):  
Nicholas Leplat ◽  
Jozef Federič ◽  
Katarína Šulková ◽  
Mária Sudolská ◽  
Florent Louis ◽  
...  
Keyword(s):  
Rate Constants ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dependent Rate ◽  
Highly Correlated ◽  
Kinetics Of

AbstractThe present study reports temperature dependent rate constantsHighly correlated

scholarly journals Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes

2003 ◽  
Vol 3 (6) ◽  
pp. 2233-2307 ◽  
Author(s):  
R. Atkinson
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Relative Rate ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dependent Rate ◽  
Temperature Ranges ◽  
Kinetics Of

Abstract. The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measurements have been made (~180-2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented. The recommended 298 K rate constants, temperature-dependent parameters, and temperature ranges over which these recommendations are applicable are listed in Table 1.

Temperature Dependent Rate Constants for the Gas-Phase Reaction between OH and CH3OCl

1996 ◽  
Vol 100 (9) ◽  
pp. 3601-3606 ◽  
Author(s):  
John N. Crowley ◽  
Pedro Campuzano-Jost ◽  
Geert K. Moortgat
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Phase Reaction ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Dependent Rate

Rate constant and activation energy determination for reaction of e−(aq) and •OH with 2-butanone and propanal

1994 ◽  
Vol 72 (4) ◽  
pp. 1116-1119 ◽  
Author(s):  
Stephen P. Mezyk
Keyword(s):  
Activation Energy ◽  
Kinetic Parameters ◽  
Rate Constants ◽  
Pulse Radiolysis ◽  
Radical Reaction ◽  
Temperature Dependent ◽  
Dependent Rate ◽  
Temperature Ranges ◽  
The Given ◽  
Energy Determination

The techniques of pulse radiolysis and absorption spectroscopy have been used to determine kinetic parameters for e−(aq) and •OH reaction with 2-butanone and propanal. The temperature dependent rate constants for hydrated electron reaction are given by ln k(T) = (28.96 ± 0.06) − (1970 ± 20)/T' (2-butanone, 275–343 K), and ln k(T) = (29.2 ± 0.2) − (2160 ± 50)/T (propanal, 275–310 K), where the given uncertainties are 1σ and only represent precision, and the rate constants are in units of M−1 s−1. For hydroxyl radical reaction over the same temperature ranges. ln k(T) = 25.32 ± 0.02) − (1460 ± 40)/T (2-butanone) and ln k(T) = (32.73 ± 0.03) − (3310 ± 100)/T (propanal).

Temperature-dependent rate constants for the reaction of ground-state chlorine with simple alkanes

1980 ◽  
Vol 84 (16) ◽  
pp. 2009-2015 ◽  
Author(s):  
R. S. Lewis ◽  
S. P. Sander ◽  
S. Wagner ◽  
R. T. Watson
Keyword(s):  
Ground State ◽  
Rate Constants ◽  
Temperature Dependent ◽  
Dependent Rate
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