Paramagnetic Character in Thin Films of Metal-Free Organic Magnets Deposited on TiO2(110) Single Crystals

2013 ◽  
Vol 117 (50) ◽  
pp. 26675-26679 ◽  
Author(s):  
Reza Kakavandi ◽  
Sabine-Antonia Savu ◽  
Andrea Caneschi ◽  
Maria Benedetta Casu
Keyword(s):  
Thin Films ◽  
Single Crystals ◽  
Metal Free ◽  
Organic Magnets

scholarly journals Giant room temperature elastocaloric effect in metal-free thin-film perovskites

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Cheng Li ◽  
Yu Hui Huang ◽  
Jian-Jun Wang ◽  
Bo Wang ◽  
Yong Jun Wu ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Room Temperature ◽  
Entropy Change ◽  
Stress Change ◽  
Chemical Doping ◽  
Metal Free ◽  
Organic Ferroelectrics ◽  
Potential Applications ◽  
Unit Stress

AbstractSolid-state refrigeration which is environmentally benign has attracted considerable attention. Mechanocaloric (mC) materials, in which the phase transitions can be induced by mechanical stresses, represent one of the most promising types of solid-state caloric materials. Herein, we have developed a thermodynamic phenomenological model and predicted extraordinarily large elastocaloric (eC) strengths for the (111)-oriented metal-free perovskite ferroelectric [MDABCO](NH4)I3 thin-films. The predicted room temperature isothermal eC ΔSeC/Δσ (eC entropy change under unit stress change) and adiabatic eC ΔTeC/Δσ (eC temperature change under unit stress change) for [MDABCO](NH4)I3 are −60.0 J K−1 kg−1 GPa−1 and 17.9 K GPa−1, respectively, which are 20 times higher than the traditional ferroelectric oxides such as BaTiO3 thin films. We have also demonstrated that the eC performance can be improved by reducing the Young’s modulus or enhancing the thermal expansion coefficient (which could be realized through chemical doping, etc.). We expect these discoveries to spur further interest in the potential applications of metal-free organic ferroelectrics materials towards next-generation eC refrigeration devices.

Phenethylammonium bismuth halides: from single crystals to bulky-organic cation promoted thin-film deposition for potential optoelectronic applications

2019 ◽  
Vol 7 (36) ◽  
pp. 20733-20741 ◽  
Author(s):  
Mehri Ghasemi ◽  
Miaoqiang Lyu ◽  
Md Roknuzzaman ◽  
Jung-Ho Yun ◽  
Mengmeng Hao ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Surface Roughness ◽  
Single Crystals ◽  
Organic Cation ◽  
Thin Film Deposition ◽  
Film Deposition ◽  
Optoelectronic Applications ◽  
Excellent Stability

The phenethylammonium cation significantly promotes the formation of fully-covered thin-films of hybrid bismuth organohalides with low surface roughness and excellent stability.

Surface acoustic wave measurements of YBa2Cu3O7−δ thin films and single crystals

1997 ◽  
Vol 70 (11) ◽  
pp. 1468-1470 ◽  
Author(s):  
R. Gaffney ◽  
C. Hucho ◽  
J. R. Feller ◽  
M. J. McKenna ◽  
B. K. Sarma ◽  
...  
Keyword(s):  
Thin Films ◽  
Acoustic Wave ◽  
Single Crystals ◽  
Surface Acoustic Wave ◽  
Wave Measurements

Electronic band structure of gallium nitride: a comparative angle-resolved photoemission study of single crystals and thin films

2002 ◽  
Vol 507-510 ◽  
pp. 223-228 ◽  
Author(s):  
L. Plucinski ◽  
T. Strasser ◽  
B.J. Kowalski ◽  
K. Rossnagel ◽  
T. Boetcher ◽  
...  
Keyword(s):  
Thin Films ◽  
Gallium Nitride ◽  
Band Structure ◽  
Single Crystals ◽  
Electronic Band Structure ◽  
Electronic Band ◽  
Photoemission Study

scholarly journals A 350 mK, 9 T scanning tunneling microscope for the study of superconducting thin films on insulating substrates and single crystals

2013 ◽  
Vol 84 (12) ◽  
pp. 123905 ◽  
Author(s):  
Anand Kamlapure ◽  
Garima Saraswat ◽  
Somesh Chandra Ganguli ◽  
Vivas Bagwe ◽  
Pratap Raychaudhuri ◽  
...  
Keyword(s):  
Thin Films ◽  
Single Crystals ◽  
Scanning Tunneling Microscope ◽  
Scanning Tunneling ◽  
Superconducting Thin Films ◽  
Tunneling Microscope ◽  
Insulating Substrates

Space-charge-limited conductivity in evaporated α-form metal-free phthalocyanine thin films

Vacuum ◽  
1998 ◽  
Vol 50 (1-2) ◽  
pp. 53-56 ◽  
Author(s):  
N Aimai ◽  
R.D. Gould ◽  
AM Saleh
Keyword(s):  
Thin Films ◽  
Space Charge ◽  
Metal Free ◽  
Space Charge Limited

Shape of piezoelectric hysteresis loop for non-ferroelastic switching

2003 ◽  
Vol 784 ◽  
Author(s):  
A. K. Tagantsev ◽  
P. Muralt ◽  
J. Fousek
Keyword(s):  
Thin Films ◽  
Electric Field ◽  
Hysteresis Loop ◽  
Single Crystals ◽  
Applied Electric Field ◽  
Piezoelectric Coefficient ◽  
Hysteresis Loops ◽  
Simple Theory ◽  
The Difference

ABSTRACTA simple theory for the shape of the piezoelectric hysteresis loops (piezoelectric coefficient d vs. applied electric field E) is developed for the case of non-ferroelelastic 180° switching in ferroelectrics. The theory provides explanations for specific features of piezoelectric hysteresis loops, which have been observed in single crystals, thin films and in ceramics in particular. The piezoelectric coefficient may show a “hump”, i.e. when E decreases from the tip of the loop down to zero, d passes through a maximum, and a “nose”, i.e. a self-crossing of the loop close to its tips. The theory also explains the difference in the coercive fields seen in the polarization and piezoelectric loops.

Growth and Crystal Structure of Alq3 Single Crystals. A new structure showing π–π and CH-π interactions.

2004 ◽  
Vol 829 ◽  
Author(s):  
Ali N. Rashid ◽  
Donald C. Craig
Keyword(s):  
Crystal Structure ◽  
Thin Films ◽  
Solid State ◽  
Single Crystals ◽  
Metal Chelate ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
The Past ◽  
Organic Light ◽  
Available Information

Tris-(8-hydroxyquinoline) aluminum III (Alq3) is a stable metal chelate that has received a great deal of attention over the past years due to its use in the fabrication of organic light emitting diodes (OLED).[1,2] Despite all the interest in this remarkable material very little information on its' solid-state properties and packing exists. Nearly all of the available information comes from studies that have been carried out on vacuum deposited thin films.[1]

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