Intrinsic Optical Activity and Conformational Flexibility: The Role of Size-Dependent Ring Morphology in Model Cycloketones

2013 ◽  
Vol 117 (47) ◽  
pp. 12382-12400 ◽  
Author(s):  
Priyanka Lahiri ◽  
Kenneth B. Wiberg ◽  
Patrick H. Vaccaro
2021 ◽  
pp. 103836
Author(s):  
Ding Tang ◽  
Leilei Zhao ◽  
Huamiao Wang ◽  
Dayong Li ◽  
Yinghong Peng ◽  
...  

2001 ◽  
Vol 703 ◽  
Author(s):  
Ho-Soon Yang ◽  
J.A. Eastman ◽  
L.J. Thompson ◽  
G.-R. Bai

ABSTRACTUnderstanding the role of grain boundaries in controlling heat flow is critical to the success of many envisioned applications of nanocrystalline materials. This study focuses on the effect of grain boundaries on thermal transport behavior in nanocrystalline yttria-stabilized zirconia (YSZ) coatings prepared by metal-organic chemical vapor deposition.


RSC Advances ◽  
2015 ◽  
Vol 5 (115) ◽  
pp. 95007-95013 ◽  
Author(s):  
A. Scelsi ◽  
B. Bochicchio ◽  
A. Smith ◽  
A. Saiani ◽  
A. Pepe

The self-assembly of an elastin-inspired triblock peptide into nanospheres highlights the important role of conformational flexibility and π–π stacking.


2011 ◽  
Vol 80 (2) ◽  
pp. 133-141 ◽  
Author(s):  
Roman Luštrik ◽  
Martin Turjak ◽  
Simona Kralj-Fišer ◽  
Cene Fišer

Interspecific interactions between surface and subterranean species may be a key determinant for species distributions. Until now, the existence of competition (including predation) between these groups has not been tested. To assess the coexistence and potential role of interspecific interactions between surface Gammarus fossarum and subterranean Niphargus timavi, and to determine their micro distributions, we conducted a series of field and laboratory observations. We aimed to determine: (1) species substrate preference, (2) whether the presence of G. fossarum influences the habitat choice of N. timavi, and (3) possible predation effects on micro habitat choice of small juveniles. Throughout a small river in SW Slovenia, N. timavi was predominantly found in leaf litter and gravel, but rarely in sand. In the sand however, we exclusively found juveniles. In contrast, surface G. fossarum sheltered mainly in leaf litter. A similar, body size dependent, micro distribution was observed in G. fossarum, where small individuals were generally found in gravel and sand. The presence of G. fossarum affected the micro distribution of juvenile, but not adult, N. timavi. In the laboratory we observed predation and cannibalism in both species. Niphargus timavi, however, appeared to be a more efficient predator than G. fossarum. In particular, juvenile N. timavi were most vulnerable to preying by adults of both species. This probably affected the distribution of juvenile N. timavi that chose finer substrates when placed with adult individuals in an aquarium with granules of different size. To understand the distribution of subterranean species, the summed effect of intraspecific interactions, as well as surface – subterranean species interactions, in particular between individuals of different size, should be taken into account.


2020 ◽  
Vol 8 (5) ◽  
pp. 1405-1417 ◽  
Author(s):  
Jiranuwat Sapudom ◽  
Khiet-Tam Nguyen ◽  
Steve Martin ◽  
Tom Wippold ◽  
Stephanie Möller ◽  
...  

Biomimetic matrix models demonstrate the role of the size-dependent effect of hyaluronan in melanoma progression and reveal an alternative explanation for in vivo findings of hyaluronan dependent melanoma growth.


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