Photoinduced Energy vs Electron Transfer Between Fe(II) and Ru(II) Bisterpyridyl Complexes in Solution and Grafted on a Gold Surface

2013 ◽  
Vol 117 (40) ◽  
pp. 20431-20439 ◽  
Author(s):  
Sébastien Liatard ◽  
Jérôme Chauvin ◽  
Damien Jouvenot ◽  
Frédérique Loiseau ◽  
Alain Deronzier
Soft Matter ◽  
2011 ◽  
Vol 7 (22) ◽  
pp. 10925 ◽  
Author(s):  
Mayreli Ortiz ◽  
Mabel Torréns ◽  
Nuria Canela ◽  
Alex Fragoso ◽  
Ciara K. O'Sullivan

2013 ◽  
Vol 118 (1) ◽  
pp. 468-475 ◽  
Author(s):  
Ezequiel de la Llave ◽  
Romain Clarenc ◽  
David J. Schiffrin ◽  
Federico J. Williams

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2893 ◽  
Author(s):  
Toshikazu Kitagawa ◽  
Takashi Kawano ◽  
Takahiro Hase ◽  
Ikuma Hayakawa ◽  
Katsuyuki Hirai ◽  
...  

The three-point adsorption of tripod-shaped molecules enables the formation of robust self-assembled monolayers (SAMs) on solid surfaces, where the component molecules are fixed in a strictly upright orientation. In the present study, SAMs of a rigid molecular tripod consisting of an adamantane core and three CH2SH groups were employed to arrange ferrocene on a gold surface through oligo(p-phenyleneethynylene) linkers. Cyclic voltammetry of the monolayers demonstrated high surface coverage of ferrocene, yet the molecular interaction among adjacent ferrocene units was negligible. This was because of the extended intermolecular distance caused by the bulky tripod framework. The rates of electron transfer from the ferrocene to the gold surface through different linker lengths were determined by electrochemical measurements, from which the decay factor for oligo(p-phenyleneethynylene) wire was evaluated.


2008 ◽  
Vol 20 (5) ◽  
pp. 513-519 ◽  
Author(s):  
Mojtaba Shamsipur ◽  
Sayed Habib Kazemi ◽  
Ali Mehdinia ◽  
Mir Fazlollah Mousavi ◽  
Hashem Sharghi

2016 ◽  
Vol 7 (5) ◽  
pp. 929-936 ◽  
Author(s):  
Tao Wei ◽  
Heng Ma ◽  
Aiichiro Nakano

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