Ionic Liquids Based on Polynitrile Anions: Hydrophobicity, Low Proton Affinity, and High Radiolytic Resistance Combined

2013 ◽  
Vol 117 (23) ◽  
pp. 7084-7094 ◽  
Author(s):  
Ilya A. Shkrob ◽  
Timothy W. Marin ◽  
James F. Wishart
Keyword(s):  
Ionic Liquids ◽  
Proton Affinity

Towards a Better Understanding of 'Delocalized Charge' in Ionic Liquid Anions

2007 ◽  
Vol 60 (1) ◽  
pp. 15 ◽  
Author(s):  
Ekaterina I. Izgorodina ◽  
Maria Forsyth ◽  
Douglas R. MacFarlane
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Melting Point ◽  
Proton Affinity ◽  
Molten Salts ◽  
Charge Delocalization ◽  
Range Of Values

One of the main characteristics that are attributed to ionic liquids (especially those with a low melting point) is that the anions comprising the ionic liquids possess a certain degree of charge delocalization as compared to anions in traditional molten salts. Based on the proton affinity equilibrium we proposed a new energetic criterion that can be used as a measure of charge delocalization. The proposed proton affinity comparison quantifies the extent to which ionic liquid anions are delocalized. Thus it should lead to a better understanding towards the design of task-specific ionic liquids. Therefore, this criterion can be applied to newly designed anions to assure that the extent of charge delocalization falls within the same range of values on the proton affinity scale as other commonly used ionic liquid anions.

Investigation of Various Ionic Liquids and Catalyst Materials for Lithium-Oxygen Batteries

2011 ◽  
pp. 110923034559006
Author(s):  
Arnd Garsuch ◽  
D. Michael Badine ◽  
Klaus Leitner ◽  
Luiz H. S. Gasparotto ◽  
Natalia Borisenko ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Lithium Oxygen Batteries

GUANIDINCONTAINING OLIGOMERIC CATIONIC POTONIC IONIC LIQUIDS WITH BIOCIDE ACTIVITY

2020 ◽  
Vol 42 (3) ◽  
pp. 218-225
Author(s):  
T.T. Alekseeva ◽  
◽  
N.V. Kozak ◽  
N.V. Yarova ◽  
◽  
...  
Keyword(s):  
Ionic Liquids
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